Skip to main content
SpringerLink
Log in

Thermodynamic Properties of Metal-Carbon Melts

  • Published:
Inorganic Materials Aims and scope

Abstract

The partial and total enthalpies of mixing of Si-C and Ni-C liquid alloys at 2000 K are determined by isoperibol calorimetry. The mixing enthalpies in these systems are found to be small and negative, in agreement with earlier results. The thermochemical properties of dilute Al-C solutions are studied at 1773 K for the first time. The mixing enthalpies of metal-carbon melts are estimated from the standard enthalpies of formation of metal carbides. The calculated mixing enthalpies of liquid metal-carbon alloys agree with experimental data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Kudin, V.G. and Makara, V.A., Thermodynamic Properties of Metal-Boron Alloys, Neorg. Mater., 2002, vol. 38, no.3, pp. 280–284 [Inorg. Mater. (Engl. Transl.), vol. 38, no. 3, pp. 216–219].

    Google Scholar 

  2. Hultgren, K., Desai, R.D., Hawkins, D.T., et al., Selected Values of the Thermodynamic Properties of the Elements, Metals Park: Am. Soc. Met., 1973.

    Google Scholar 

  3. Witusiewicz, V.T., Enthalpies of Formation of Silicon-Carbon Melts, in Sovershenstvovanie tekhnologii polucheniya litykh materialov (Advances in the Technology of Cast Materials), Kiev: Akad. Nauk Ukr. SSR, 1986, pp. 8–11.

    Google Scholar 

  4. Binary Alloy Phase Diagrams, Massalski, T.B., Ed., Metals Park: ASM International 1990, 2nd ed.

    Google Scholar 

  5. Il’inykh, N.I., Moiseev, G.K., and Vatolin, N.A., Thermodynamic Modeling in the Si-C System, Rasplavy, 1998, no. 6, pp. 29–32.

  6. Witusiewicz, V.T., Thermodynamic Properties of Liquid Alloys of 3d-Transition Metals with Metalloids (Silicon, Carbon, and Boron), J. Alloys Compd., 1994, vol. 203, pp. 103–116.

    CAS  Google Scholar 

  7. Pupynin, V.N., Jeng-Ji, S., Polyakov, A.Yu., and Samarin, A.M., Component Activities in Liquid Nickel-Carbon Alloys, in Metallurgiya, metallovedenie i fizikokhimicheskie metody issledovanii (Metallurgy, Metal Physics, and Physicochemical Characterization), Moscow: Inst. Metallurgii Akad. Nauk SSSR, 1962, pp. 155–159.

    Google Scholar 

  8. Diagrammy sostoyaniya metallicheskikh sistem (Phase Diagrams of Metallic Systems), Lyakishev, N.P., Ed., Moscow: Mashinostroenie, 2001.

    Google Scholar 

  9. Samsonov, G.V. and Vinitskii, I.M., Tugoplavkie soedineniya (Refractory Compounds), Moscow: Metallurgiya, 1976.

    Google Scholar 

  10. Meshel, S.V. and Kleppa, O.J., Thermochemistry of Alloys Transition Metals and Lanthanide Melts with Some IIIB and IVB Elements in the Periodic Table, J. Alloys Compd., 2001, vol. 321, no.1, pp. 183–200.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Shevchenko National University, Volodymyrs’ka ul. 64, Kyiv, 01033, Ukraine

    V. G. Kudin & V. A. Makara

Authors
  1. V. G. Kudin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Makara
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Neorganicheskie Materialy, Vol. 41, No. 6, 2005, pp. 682–686.

Original Russian Text Copyright © 2005 by Kudin, Makara.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kudin, V.G., Makara, V.A. Thermodynamic Properties of Metal-Carbon Melts. Inorg Mater 41, 591–594 (2005). https://doi.org/10.1007/s10789-005-0175-0

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10789-005-0175-0

Keywords

Search

Navigation