Skip to main content
SpringerLink
Log in

Effect of mechanical activation on the reactivity of powder copper

  • Published:
Inorganic Materials Aims and scope

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

Mechanical activation is found to enhance the reactivity of copper powder with acetic acid. The milling-induced increase in the thermal effect of the reaction between Cu and acetic acid is shown to be associated with the activation of the molecular oxygen involved in the reaction. The activation is due to the presence of lattice oxygen with increased bond energies.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Morokhov, I.D., Petinov, V.I., Trusov, L.I., and Petrunin, V.F., Structure and Properties of Small Metallic Particles, Usp. Fiz. Nauk, 1981, vol. 133, no. 4, pp. 653–692.

    Google Scholar 

  2. Heinike, G., Tribochemistry, Berlin: Akademie, 1984. Translated under the title Tribokhimiya, Moscow: Mir, 1987.

    Google Scholar 

  3. Ivanov, G.V., Yavorovskii, N.A., Kotov, Yu. A., et al., Self-propagating Sintering of Ultrafine Metallic Powders, Dokl. Akad. Nauk SSSR, 1984, vol. 275, no. 4, pp. 873–875.

    Google Scholar 

  4. Poluboyarov, V.A., Andryushkova, O.V., Avvakumov, E.G., et al., Origin of Optical Absorption in the Diffuse Reflectance Spectra of Mechanically Activated Oxides, Sib. Khim. Zh., 1993, no. 1, pp. 119–125.

  5. Poluboyarov, V.A., Andryushkova, O.V., Avvakumov, E.G., et al., Experimental Study of Processes Induced by Mechanical Activation of Oxides, Fiz.-Tekh. Probl. Razrabotki Poleznykh Iskopaemykh, 1993, no. 1, pp. 93–107.

  6. Makarova, O.V., Yur’eva, T.M., Kustova, G.N., et al., Reaction of Hydrogen with Copper-Containing Oxide Catalysts: I. State of Copper Chromite and Its Activity for Acetone Hydrogenation to Isopropanol, Kinet. Katal., 1993, vol. 34, no. 4, p. 681.

    Google Scholar 

  7. Makarova, O.V., Yur’eva, T.M., Plyasova, L.M., et al., Reaction of Hydrogen with Copper-Containing Oxide Catalysts: II. Reactions of Hydrogen-Reduced Copper Chromite and Copper Zinc Oxide with Acetone and Carbon Monoxide, Kinet. Katal., 1994, vol. 35, no. 3, p. 406.

    Google Scholar 

  8. Sirotkina, E.E, Kobotaeva, N.S., and Svarovskaya, N.V., Reactivity of Copper Powders, Materialy V vserossiiskoi konferentsii po fizikokhimii ul’tradispersnykh sistem (Proc. V All-Russia Conf. on the Physical Chemistry of Ultrafine-Particle Systems), Yekaterinburg, 2000, p. 51.

  9. Koch, C.C., The Synthesis and Structure of Nanocrystalline Materials Produced by Mechanical Attrition: A Review, Nanostruct. Mater., 1993, vol. 2, pp. 109–129.

    Google Scholar 

  10. Koch, C.C., Synthesis of Nanostructured Materials by Mechanical Milling: Problems and Opportunities, Nanostruct. Mater., 1997, vol. 9, pp. 13–22.

    Google Scholar 

  11. Oleszak, D. and Shingu, P.H., Nanocrystalline Metals Prepared by Low Energy Ball Milling, J. Appl. Phys., 1996, vol. 79, no. 6, pp. 2976–2980.

    Google Scholar 

  12. Avvakumov, E.G., Potkin, A.R., and Samarin, O.I., USSR Inventor’s Certificate no. 975068, Byull. Izobret., 1982, no. 43.

  13. Karnaukhov, A.P., Adsorbtsiya. Tekstura dispersnykh i poristykh materialov (Adsorption and Texture of Fine-Particle and Porous Materials), Novosibirsk: Nauka, 1999.

    Google Scholar 

  14. Handbook of X-ray Photoelectron Spectroscopy, Wagner, C.D. et al., Eds., Eden Prairie: Perkin-Elmer, 1978.

    Google Scholar 

  15. Ripan, R. and Ceteanu, I., Chimia metalelor, Bucharest: Editura Didactica si Pedagogica, 1969. Translated under the title Neorganicheskaya khimiya, Moscow: Mir, 1972.

    Google Scholar 

  16. Cherepanov, A.N., Solonenko, O.P., Poluboyarov, V.A., et al., Application of Uitra-Fine Powders of Refractory Compounds for Improving the Mechanical Properties of Plasma-Sprayed Coating, Proc. XV Symp. on Plasma Chemistry, Orleans, 2001, vol. 6, pp. 2527–2531.

    Google Scholar 

  17. Poluboyarov, V.A., Lapin, A.E., Korotaeva, Z.A., et al., Effect of Mechanical Activation on the Strength of Plasma-Sprayed Metallic Coatings and Reactivity of Metallic Copper, Fiz. Mezomekh., 2002, vol. 5, no. 2, pp. 97–102.

    Google Scholar 

  18. Poluboyarov, V.A., Lapin, A.E., Korotayeva, Z.A., et al., The Effect of Mechanical Action on Strength Characteristics of Plasmochemical Metal Coatings and the Reactivity of Metal Copper, Int. Workshop Mesomechanics: Foundations and Applications, Tomsk, 2001, p. 56.

  19. Poluboyarov, V.A., Lapin, A.E., Korotayeva, Z.A., et al., The Effect of Mechanical Action on the Reactivity of Metal Copper, Int. Conf. on the Fundamental Bases of Mechanochemical Technologies, Novosibirsk, 2001, p. 67.

  20. Nechaeva, S.I., Chalykh, A.E., Toporov, Yu. P., and Yaroslavtseva, E.M., Phase Transformations of Polyamide Dispersed with Chromium Hexaaquachloride, Polym. Sci., Ser. A, 1994, vol. 36, no. 5, pp. 619–624.

    Google Scholar 

  21. Suryanarayana, C., Mechanical Alloying and Milling, Prog. Mater. Sci., 2001, vol. 46, pp. 1–184.

    Google Scholar 

  22. Vasil’ev, L.S. and Lomaeva, S.F., Mechanisms Limiting Size Reduction in Powders Produced by Mechanical Milling, Fiz. Met. Metalloved., 2002, vol. 93, no. 2, pp. 1–9.

    Google Scholar 

  23. Guan, R., Hashimoto, H., and Yoshida, T., Electron-Microscopic Study of the Structure of Metastable Oxides Formed in the Initial Stage of Copper Oxidation: I. Cu4O, Acta Crystallogr., Sect. B: Struct. Sci., 1984, vol. 40, pp. 109–114.

    Google Scholar 

  24. Guan, R., Hashimoto, H., and Kuo, K.H., Electron-Microscopic Study of the Structure of Metastable Oxides Formed in the Initial Stage of Copper Oxidation: II. Cu8O, Acta Crystallogr., Sect. B: Struct. Sci., 1984, vol. 40, pp. 560–566.

    Google Scholar 

  25. Guan, R., Hashimoto, H., Kuo, K.H., and Yoshida, T., Electron-Microscopic Study of the Structure of Metastable Oxides Formed in the Initial Stage of Copper Oxidation: IV. Cu4O-S1 and Cu4O-S2, Acta Crystallogr., Sect. B: Struct. Sci., 1987, vol. 34, pp. 343–346.

    Google Scholar 

  26. Sadykov, V.A, Structural Perfection and Microstructure of Oxidation Catalysts, Doctoral (Chem.) Dissertation, Novosibirsk, 1998.

  27. Barr, T.L., Studies in Differential Charging, J. Vac. Sci. Technol. A, 1989, vol. 7, no. 3, pp. 1677–1683.

    Google Scholar 

  28. Bukhtiyarov, V.I., Prosvirin, I.P., and Kvon, R.I., Application of Differential Charging for Analysis of Electronic Properties of Supported Silver, J. Electron Spectrosc. Relat. Phenom., 1996, vol. 77, pp. 7–14.

    Google Scholar 

  29. Bukhtiyarov, V.I., Prosvirin, I.P., Tikhomirov, E.P., et al., In Situ Study of Selective Oxidation of Methanol to Formaldehyde over Copper, React. Kinet. Catal. Lett., 2003, vol. 79, no. 1, pp. 181–188.

    Article  Google Scholar 

  30. Knop-Gericke, A., Hävecker, M., Shedel-Niedrig, Th., and Schlögl, R., Characterisation of Active Phases of a Copper Catalyst for Methanol Oxidation under Reaction Conditions: An In Situ X-ray Absorption Spectroscopy Study in the Soft Energy Range, Topics Catal., 2001, vol. 15, p. 27.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid-State Chemistry and Mechanochemistry Siberian Division, Russian Academy of Sciences, ul. Kutateladze 18, 630128, Novosibirsk, Russia

    V. A. Poluboyarov, A. E. Lapin & Z. A. Korotaeva

  2. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, 630090, Novosibirsk, Russia

    I. P. Prosvirin & V. I. Bukhtiyarov

  3. Institute of Oil Chemistry, Siberian Division, Russian Academy of Sciences, Akademicheskii pr. 3, 634055, Tomsk, Russia

    E. E. Sirotkina & N. S. Kobotaeva

Authors
  1. V. A. Poluboyarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. E. Lapin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Z. A. Korotaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. P. Prosvirin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. I. Bukhtiyarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. E. E. Sirotkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. N. S. Kobotaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Neorganicheskie Materialy, Vol. 41, No. 2, 2005, pp. 151–161.

Original Russian Text Copyright © 2005 by Poluboyarov, Lapin, Korotaeva, Prosvirin, Bukhtiyarov, Sirotkina, Kobotaeva.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Poluboyarov, V.A., Lapin, A.E., Korotaeva, Z.A. et al. Effect of mechanical activation on the reactivity of powder copper. Inorg Mater 41, 110–119 (2005). https://doi.org/10.1007/s10789-005-0029-9

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10789-005-0029-9

Keywords

Search

Navigation