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Preparation and properties of orthorhombic TlInS2

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Abstract

A procedure is described for crystal growth of orthorhombic TlInS2. The lattice parameters of the grown crystals are a = 6.88 Å, b = 14.04 Å, and c = 4.02 Å (sp. gr. P2221, Z = 4, ρx = 6.59 g/cm3). The dielectric permittivity of the crystals is measured from 170 to 300 K. The spectral dependence of the 300-K photocurrent through the crystals indicates that orthorhombic TlInS2 is a wide-gap semiconductor. Its band gap, E g = 2.52 ± 0.01 eV, slightly exceeds that of monoclinic TlInS2.

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REFERENCES

  1. Muller, D., Poltmann, F., and Hahn, H., Zur Structur ternarer Chalcogenide des Talliums mit Aliminium, Gallium und Indium, Z. Naturforsch., B: Chem. Sci., 1974, vol. 29, no. 1/2, pp. 117–118.

    Google Scholar 

  2. Henkel, W., Hochheimer, H.D., Carlone, C., et al., High-Pressure Raman Study of the Ternary Chalcogenides TlGaS2, TlGaSe2, TlInS2, and TlInSe2, Phys. Rev. B: Condens. Matter, 1982, vol. 26, no. 6, pp. 3211–3221.

    CAS  Google Scholar 

  3. Hahn, H. and Wellman, B., Uber ternare Chalkogenide des Talliums mit Gallium und Indium, Naturwissenschaften, 1967, vol. 54, no. 2, p. 42.

    Google Scholar 

  4. Range, K.-J., Engert, G., Muller, W.A., and Weiss, A., Hochdrucksynthese und Kristallstrukturen von TlInS2-II und TlInS2-III, Z. Naturforsch., B: Chem. Sci., 1974, vol. 29, no. 3/4, pp. 181–185.

    CAS  Google Scholar 

  5. Aliev, S.N., Nadjafov, A.I., and Alekperov, O.Z., Preparation and Properties of Hexagonal TlInS2, Izv. Akad. Nauk SSSR, Neorg. Mater., 1991, vol. 27, no. 3, pp. 621–622.

    CAS  Google Scholar 

  6. Isaacs, T.I., Determination of the Crystal Symmetry of the Polymorphs of Thallium Indium Disulphide, TlInS2, Z. Kristallogr., 1975, vol. 141, no. 1/2, pp. 104–108.

    Article  CAS  Google Scholar 

  7. Guseinov, G.D., Kerimova, E.M., Bidzinova, S.M., et al., Physical Properties of New Ternary Semiconductor Chalcogenides, in Nekotorye voprosy eksperimental’noi i teoreticheskoi fiziki (Current Topics in Experimental and Theoretical Physics), Baku: Elm, 1977, pp. 155–170.

    Google Scholar 

  8. Golovei, M.I., Tkachenko, V.I., Nekrasova, I.M., et al., Phase Equilibria near TlInS2, TlInSe2, TlGaS2, and TlGaSe2, V Vsesoyuznaya konferentsiya po khimii, fizike i tekhnicheskomu primeneniyu khal’kogenidov (V All-Union Conf. on the Physics, Chemistry, and Technological Applications of Chalcogenides), Baku, 1979, p. 37.

  9. Hocnheimer, H.D., Gmelin, E., Mensing, Ch., et al., AC Conductivity, Calorimetric, X-ray, and Raman Study of the Hexagonal Phase TInS2-III, Phys. Status Solidi A, 1985, vol. 88, no. 1, pp. 43–48.

    Google Scholar 

  10. Kröger, F.A., The Chemistry of Imperfect Crystals, Amsterdam: North-Holland, 1964.

    Google Scholar 

  11. Aliev, S.N., Nadjafov, A.I., and Alekperov, O.Z., Effect of Sulfur Vacancies on the Photoconductivity of TlInS2 Crystals, Neorg. Mater., 1992, vol. 28, no. 7, pp. 1566–1567.

    CAS  Google Scholar 

  12. Bokii, G.B. and Porai-Koshits, M.A., Rentgenostrukturnyi analiz (X-ray Crystallography), Belov, N.V., Ed., Moscow: Mosk. Gos. Univ., 1964.

    Google Scholar 

  13. Julien-Pourol, M. and Guittard, M., Etude cristallochimique des combinaisons ternaires argent-terre rare-soufre ou sélénium, situées le long des binaires Ag2X-L2X2, Ann. Chim. (Paris), 1973, vol. 8, pp. 139–145.

    Google Scholar 

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Translated from Neorganicheskie Materialy, Vol. 41, No. 2, 2005, pp. 138–142.

Original Russian Text Copyright © 2005 by Nadjafov, Alekperov, Guseinov.

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Nadjafov, A.I., Alekperov, O.Z. & Guseinov, G.G. Preparation and properties of orthorhombic TlInS2 . Inorg Mater 41, 98–101 (2005). https://doi.org/10.1007/s10789-005-0026-z

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  • DOI: https://doi.org/10.1007/s10789-005-0026-z

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