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Vapor Pressure Measurements and Predictions for Binary Systems Containing Ethyl Octanoate or Ethyl Dodecanoate as Biodiesels and n-Tetradecane as Petrodiesel Compound

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Abstract

The present work falls within the research line focused on the phase equilibria of binary mixtures comprising typical compounds, widely present in biodiesel/petrodiesel blends. The study was performed by investigating the liquid–vapor equilibria and thermodynamic properties of two binary systems: ethyl octanoate (1) + n-tetradecane (2) and ethyl dodecanoate (1) + n-tetradecane (2) using experimental and computational methods. The experimental data of vapor pressures were measured through a static apparatus at nine temperatures from (373.15 K and 453.15 K) with an interval of 10 K. The obtained experimental data are used to determine the activity coefficients (γi) and excess molar Gibbs energies (GE) of the investigated binary mixtures by applying the Redlich–Kister equation according to Barker’s method. Positive values of the excess molar Gibbs energy are obtained for all the investigated constant temperatures and over the whole composition range. The obtained GE values were correlated by using two semi-predictive models (NRTL and Heil). The prediction displays agreement with the experimental data obtained with Barker’s method. The present work provides a set of thermodynamic data that may be very useful for the development of eco-friendly alternative biodiesel.

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Funding

The authors declare that they have received no specific grant from any funding agency in the public, commercial, or not-for-profit sectors.

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Authors and Affiliations

  1. Ecole Supérieure du Matériel ESM, Beau-Lieu, BP 188, Alger, Algeria

    Fateh Chalghoum, Mokhtar Benziane & Ahmed Amin Toazi

  2. Energetic Materials Laboratory (EMLab), Teaching and Research Unit of Energetic Processes, Ecole Militaire Polytechnique, Bordj El-Bahri, BP 17, 16046, Algiers, Algeria

    Djalal Trache

  3. Laboratoire des Multimatériaux et Interfaces, UMR 5615, Université Claude Bernard, Lyon1, 43 Bd du 11 Novembre 1918, 69622, Villeurbanne, France

    Ilham Mokbel & Jacques Jose

  4. Université de Lyon, 42023, Saint Etienne, France

    Ilham Mokbel

Authors
  1. Fateh Chalghoum
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  2. Mokhtar Benziane
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  3. Djalal Trache
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  4. Ahmed Amin Toazi
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  5. Ilham Mokbel
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  6. Jacques Jose
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Contributions

FC: Conceptualization, Methodology, Resources, Investigation, data treatment, Writing-Original Draft. MB: Conceptualization, Methodology, Resources, Investigation, Writing-Original Draft. DT: Conceptualization, Review & Editing. AAT, IM, and JJ: Review & Editing the manuscript draft. All authors have approved the initial version of the article.

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Correspondence to Djalal Trache.

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Chalghoum, F., Benziane, M., Trache, D. et al. Vapor Pressure Measurements and Predictions for Binary Systems Containing Ethyl Octanoate or Ethyl Dodecanoate as Biodiesels and n-Tetradecane as Petrodiesel Compound. Int J Thermophys 44, 157 (2023). https://doi.org/10.1007/s10765-023-03265-4

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  • DOI: https://doi.org/10.1007/s10765-023-03265-4

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