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Experimental Study of VLE Properties of n-Tetradecane in the Supercritical Binary Solvent (0.367 Propane/0.633 n-Butane)

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Abstract

A high-temperature and high-pressure optical cell VLE apparatus has been applied to measure phase equilibrium properties of n-tetradecane in the supercritical binary solvent (0.367propane + 0.633 n-butane mass fraction) at temperatures of 413.15 K, 433.15 K, and 453.15 K between of pressures (0.9 and 6.6) MPa. The combined expanded uncertainty of the temperature, pressure, and concentration measurements at 0.95 confidence level with a coverage factor of k = 2 is estimated to be 0.15 K, 0.0022, and 0.035, respectively. The critical parameters (TC, PC, \(w_{C}\)) were determined based on the measured isothermal phase equilibrium data of the ternary system n-tetradecane + propane/n-butane. It is shown that the critical temperature and pressure of the n-tetradecane + propane/n-butane system increases with concentration of n-tetradecane increases.

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Acknowledgements

The work was financially supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of the state assignment No. 075-01508-23-00 of December 29, 2022 (Supercritical fluid technologies in polymer processing FZSG-2023-0007). The study was carried out using the equipment of the Center for Collective use «Nanomaterials and Nanotechnology» of the Kazan National Research Technological University.

Funding

The Ministry of Science and Higher Education of the Russian Federation (075-01508-23-00) and (FZSG-2023-0007).

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Authors and Affiliations

  1. Kazan National Research Technological University, Kazan, Russian Federation

    Vener F. Khairutdinov, Ilnar Sh. Khabriev, Talgat R. Akhmetzyanov, Lenar Yu. Yarullin, Farizan R. Gabitov & Ilmutdin M. Abdulagatov

  2. Department of Physical and Organic Chemistry, Dagestan State University, Makhachkala, Russian Federation

    Ilmutdin M. Abdulagatov

  3. Geothermal and Renewal Energy Institute of the High Temperature Joint Institute of the Russian Academy of Sciences, Makhachkala, Russian Federation

    Ilmutdin M. Abdulagatov

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  1. Vener F. Khairutdinov
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Contributions

VFK: investigation, supervision and editing software; ISK: formal analysis, software; TRA: writing—review and editing software; LYY: investigation, resources; FRG: conceptualization, methodology; IMA: writing—original draft.

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Correspondence to Ilmutdin M. Abdulagatov.

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Khairutdinov, V.F., Khabriev, I.S., Akhmetzyanov, T.R. et al. Experimental Study of VLE Properties of n-Tetradecane in the Supercritical Binary Solvent (0.367 Propane/0.633 n-Butane). Int J Thermophys 44, 114 (2023). https://doi.org/10.1007/s10765-023-03220-3

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