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Low Temperature Heat Capacity Study of Co2(bdc)2(dabco)

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Abstract

Temperature dependence of molar heat capacity Cp of Co2(C8H4O4)2·C6H12N2 was first measured by vacuum adiabatic calorimetry in the temperature range of 5.4–303 K. Two anomalies at 11 K and 80 K have been identified. The obtained Cp values were compared with those for Zn2(C8H4O4)2·C6H12N2 and Ni2(C8H4O4)2·C6H12N2. Spin–phonon interaction between lattice vibrations of Co2(C8H4O4)2.C6H12N2 and electron spins of Co2+ was revealed.

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Acknowledgements

The authors thank D.G. Samsonenko for providing samples for research. The research was supported by the Russian Foundation for Basic Research, No. 20-03-00089 and the Ministry of Science and Higher Education of the Russian Federation, No. 121031700313-8.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Lavrentyev Av., 3, Novosibirsk, Russian Federation, 630090

    Denis P. Pishchur, Nikolay B. Kompankov & Svetlana G. Kozlova

  2. Belgorod State Technological University Named After V.G. Shukhov, Kostukov Av., 46, Belgorod, Russian Federation, 308012

    Svetlana G. Kozlova

Authors
  1. Denis P. Pishchur
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  2. Nikolay B. Kompankov
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  3. Svetlana G. Kozlova
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Contributions

DPP and NSC carried out heat capacity measurements and edited the article. SGK analyzed all the data and wrote the original manuscript.

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Correspondence to Svetlana G. Kozlova.

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Pishchur, D.P., Kompankov, N.B. & Kozlova, S.G. Low Temperature Heat Capacity Study of Co2(bdc)2(dabco). Int J Thermophys 43, 5 (2022). https://doi.org/10.1007/s10765-021-02935-5

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  • DOI: https://doi.org/10.1007/s10765-021-02935-5

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