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Measurement and Correlation of the Thermal Conductivity of cis-1,1,1,4,4,4-hexafluoro-2-butene

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Abstract

New experimental data for the thermal conductivity of cis-1,1,1,4,4,4-hexafluoro-2-butene (R-1336mzz(Z)) are reported for vapor, liquid, and supercritical states. These data were obtained with transient hot-wire apparatus over the temperature range from 192 K to 498 K and at pressures from 0.05 MPa to 69 MPa. These data were used to develop a wide-range correlation for the thermal conductivity of the vapor, liquid, and supercritical fluid. The experimental data reported here have an uncertainty of 1 % for the liquid and supercritical regions (densities above 600 kg·m−3), 1.5 % for vapor and supercritical regions (pressures greater than or equal to 1 MPa and densities less than 200 kg·m−3), 3 % for supercritical states (densities between 200 kg·m−3 and 600 kg·m−3), and 3 % for vapor and supercritical states (pressures below 1 MPa). The thermal-conductivity correlation developed in this work is estimated to have an expanded relative uncertainty, at a 95 % confidence level, ranging from approximately 1.4 % to 4.2 % depending on the temperature and pressure, with larger uncertainties in the critical region.

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Acknowledgements

We thank Konstantin Kontomaris of Chemours for the sample of R-1336mzz(Z) studied here. We thank Mark McLinden of NIST for sample preparation that included the freeze–thaw degassing of the sample, and Tara Lovestead of NIST for characterization of the sample purity.

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  1. Thermophysical Properties of Fluids Group, National Institute of Standards and Technology, 325 Broadway, Boulder, CO, 80305-3337, USA

    Richard A. Perkins & Marcia L. Huber

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  1. Richard A. Perkins
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  2. Marcia L. Huber
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Correspondence to Richard A. Perkins.

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Perkins, R.A., Huber, M.L. Measurement and Correlation of the Thermal Conductivity of cis-1,1,1,4,4,4-hexafluoro-2-butene. Int J Thermophys 41, 103 (2020). https://doi.org/10.1007/s10765-020-02681-0

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