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Isothermal Vapor–Liquid Equilibrium Data for Water + Diisopropanolamine, Water + N-Methyldiethanolamine and Diisopropanolamine + N-Methyldiethanolamine Systems

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Abstract

Accurate modeling of thermodynamic vapor–liquid equilibrium of aqueous amines and amine mixtures is essential for the design of new CO2 capture processes. Isothermal vapor–liquid equilibrium data were measured for the binary systems of water + diisopropanolamine (DIPA), water + N-methyldiethanolamine (MDEA) and DIPA + MDEA by using headspace gas chromatography at 423 K. The DIPA + MDEA system has azeotrope. The experimental binary vapor–liquid equilibrium data of water + DIPA, water + MDEA and DIPA + MDEA binary systems were well correlated with NRTL model.

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Acknowledgments

This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) and the Ministry of Trade, Industry and Energy (MOTIE) of the Republic of Korea (No. 20152020201130).

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Authors and Affiliations

  1. Department of Chemical and Biomolecular Engineering, Seoul National University of Science and Technology, Seoul, 01811, Korea

    Jaeseok Na & Hun Yong Shin

  2. Climate Change Research Division, Korea Institute of Energy Research, Daejeon, 34129, Korea

    Byoung-Moo Min, Jong-Ho Moon & Jong-Seop Lee

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  1. Jaeseok Na
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  2. Byoung-Moo Min
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  3. Jong-Ho Moon
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  4. Jong-Seop Lee
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Correspondence to Hun Yong Shin.

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Special Issue: Advances in Thermophysical Properties.

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Na, J., Min, BM., Moon, JH. et al. Isothermal Vapor–Liquid Equilibrium Data for Water + Diisopropanolamine, Water + N-Methyldiethanolamine and Diisopropanolamine + N-Methyldiethanolamine Systems. Int J Thermophys 39, 96 (2018). https://doi.org/10.1007/s10765-018-2415-y

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  • DOI: https://doi.org/10.1007/s10765-018-2415-y

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