Abstract
A collimated surface acoustic wave (SAW) circles around the equator of a sphere hundreds of times. Because of the long distance travel of the collimated SAW, a small change in the SAW propagation caused by the environment of the sphere can be accumulated as a measurable range in amplitude and/or in delay time. So, a spherical SAW device enables highly sensitive water-vapor measurements. In this paper, deep sub \(\upmu \hbox {mol}{\cdot }\hbox {mol}^{-1}\) water-vapor detection by 1 mm diameter quartz crystal ball SAW sensors is described. To measure such a low water-vapor concentration in real time, it is necessary to compensate the temperature dependence of the ball SAW sensor, which is about 20 \(\hbox {ppm}{\cdot }^{\circ }\hbox {C}^{-1}\) in delay time change. A dual-frequency burst analog detector was developed for the temperature compensation in real time. By using a harmonic SAW sensor, which was excited by 80 MHz and 240 MHz at the same time, it was confirmed that the delay time drift for a temperature range of \(21.0\, ^{\circ }\hbox {C} \pm 1.0\,^ {\circ }\hbox {C}\) became less than 0.05 ppm in delay time change. By using dual-ball SAW sensors (which included a 150 MHz sensor with a water-vapor sensitive layer and a 240 MHz sensor as a reference), water-vapor concentrations from 0.1 \(\upmu \hbox {mol}{\cdot }\hbox {mol}^{-1}\) to \(5\; \upmu \hbox {mol}{\cdot }\hbox {mol}^{-1}\) were successfully measured. It appears that the delay time change is proportional to the square root of the water-vapor concentration. The detection limit determined by the electrical noise of the system was estimated at \(0.01\; \upmu \hbox {mol}{\cdot }\hbox {mol}^{-1}\).
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This work was supported in part by Ball Semiconductor Incorporated in Texas, U.S.A. in early times. One of the authors (N. T.) gratefully acknowledges Akihito Ishikawa who was the CEO of the company.
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Takeda, N., Oizumi, T., Tsuji, T. et al. Deep Sub-micro \(\hbox {mol}{\cdot }\hbox {mol}^{-1}\) Water-Vapor Measurement by Dual-Ball SAW Sensors for Temperature Compensation. Int J Thermophys 36, 3440–3452 (2015). https://doi.org/10.1007/s10765-015-1967-3
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DOI: https://doi.org/10.1007/s10765-015-1967-3