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Temperature Coefficients of the Refractive Index for Complex Hydrocarbon Mixtures

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Abstract

Temperature coefficients of the refractive index (\(\mathrm{d}n/\mathrm{d}T\)) in the \(25\,^{\circ }\mathrm{C}\) to \(35\,^{\circ }\mathrm{C}\) temperature interval for hydrocarbon mixtures containing as many as 14 compounds were investigated in this work. The measured \(-\mathrm{d}n/\mathrm{d}T\) of the mixtures were compared with calculations based on the values for each compound and their concentrations. Differences of about 1 % between measured and calculated values were observed for all mixtures. The additivity of \(-\mathrm{d}n/\mathrm{d}T\) for these hydrocarbons enables preparation of surrogate fuels that are formulated to have properties like those of specific diesel fuels.

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References

  1. L. Starck, B. Lecointe, N. Jeuland, Fuel 89, 3069 (2010)

    Article  Google Scholar 

  2. B.G. Bunting, S.J. Eaton, J. Storey, C. Fairbridge, K. Mitchell, R.W. Crawford, T. Gallant, J. Franz, M. Alnaijar, SAE paper 2008-01-2406 (2008)

  3. R.R. Maly, V. Schaefer, H. Hass, G.F.B. Cahill, P. Rouveirolles, A. Röj, R. Wegener, X. Montagne, A.D. Pancrazio, J. Kashdan, SAE paper 2007-01-0035 (2007)

  4. V. Hosseini, W. Neill, H. Guo, C.E. Dumitrescu, W. Chippior, C. Fairbridge, K. Mitchell, SAE paper 2010-01-2168 (2010)

  5. B.G. Bunting, S.J. Eaton, R.W. Crawford, T. Gallant, SAE paper, 2009-01-2645 (2009)

  6. C.E. Dumitrescu, W.S. Neill, H. Guo, V. Hosseini, W. Chippior, ASME paper ICEF2010-35194 (2010)

  7. M.R. Riazi, Y.A. Roomi, Ind. Eng. Chem. Res. 40, 1975 (2001)

    Article  Google Scholar 

  8. F.M. Vargas, W.G. Chapman, Fluid Phase Equilib. 290, 103 (2010)

    Article  Google Scholar 

  9. J.S. Buckley, Fuel Sci. Technol. Int. 14, 55 (1996)

    Article  Google Scholar 

  10. J.S. Buckley, G.J. Hirasaki, Y. Liu, S. Von Drasek, J.-W. Wang, B.S. Gill, Pet. Sci. Technol. 16, 251 (1998)

    Article  Google Scholar 

  11. J.S. Buckley, Energy Fuels 13, 328 (1999)

    Article  Google Scholar 

  12. S.D. Taylor, J. Czarnecki, J. Masliyah, Fuel 80, 2013 (2001)

    Article  Google Scholar 

  13. M.P.P. Castro, A.A. Andrade, R.W.A. Franco, P.C.M.L. Miranda, M. Sthel, H. Vargas, R. Constantino, M.L. Baesso, Chem. Phys. Lett. 411, 18 (2005)

    Article  ADS  Google Scholar 

  14. J.H. Rohling, J. Shen, J. Zhou, C.E. Gu, A.N. Medina, M.L. Baesso, J. Appl. Phys. 99, 103107 (2006)

    Article  ADS  Google Scholar 

  15. M.L. Baesso, J. Shen, R.D. Snook, J. Appl. Phys. 75, 3732 (1994)

    Article  ADS  Google Scholar 

  16. T. Honma, N. Ito, V. Dimitrov, T. Komatsu, J. Appl. Phys. 105, 053105 (2009)

    Article  ADS  Google Scholar 

  17. Q. Wen, J. Shen, Z. Shi, E. Dy, K.H. Michaelian, C. Fairbridge, N.G.C. Astrath, J.H. Rohling, M.L. Baesso, Chem. Phys. Lett. 539–540, 54 (2012)

    Article  Google Scholar 

  18. H. Lorentz, Weid. Ann. 9, 641 (1880)

    Article  MATH  Google Scholar 

  19. V.V. Sechenyh, J.-C. Legros, V. Shevtsova, J. Chem. Thermodyn. 43, 1700 (2011)

    Article  Google Scholar 

  20. V.V. Sechenyh, J.-C. Legros, V. Shevtsova, J. Chem. Eng. Data 57, 1036 (2012)

    Article  Google Scholar 

  21. A. Steimacher, A.N. Medina, A.C. Bento, J.H. Rohling, M.L. Baesso, V.C.S. Reynoso, S.M. Lima, M.N. Petrovich, D.W. Hewak, J. Non-Cryst. Solids 348, 240 (2004)

    Article  ADS  Google Scholar 

  22. G. Abbate, A. Attanasio, U. Bernini, E. Ragozzino, F. Somma, J. Phys. D: Appl. Phys. 9, 1945 (1976)

    Article  ADS  Google Scholar 

  23. C.J. Mueller, W.J. Cannella, T.J. Bruno, B. Bunting, H.D. Dettman, J.A. Franz, M.L. Huber, M. Natarajan, W.J. Pitz, M.A. Ratcliff, K. Wright, Energy Fuels 26, 3284 (2012)

    Article  Google Scholar 

Download references

Acknowledgments

Support from the Government of Canada’s Program of Energy Research and Development (PERD) Program 1.1.3: Petroleum Conversion for Cleaner Air is gratefully acknowledged.

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Correspondence to Jun Shen.

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Rafal Gieleciak: On leave from Institute of Chemistry, The University of Silesia, 9 Szkolna Street, 40-006 Katowice, Poland.

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Wen, Q., Shen, J., Gieleciak, R. et al. Temperature Coefficients of the Refractive Index for Complex Hydrocarbon Mixtures. Int J Thermophys 35, 930–941 (2014). https://doi.org/10.1007/s10765-014-1604-6

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  • DOI: https://doi.org/10.1007/s10765-014-1604-6

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