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Study of (Solid–Liquid) Phase Equilibria for Mixtures of Energetic Material Stabilizers and Prediction for Their Subsequent Performance

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Abstract

Solid-liquid equilibria for three binary mixtures of 2-nitrodiphenylamine (1) + diphenylamine (2), ethyl centralite (1) + N-ethyl-4-nitro-N-nitrosoaniline (2), and 2,2\(^{\prime }\)-dinitrodiphenylamine (1) + N-ethyl-4-nitro-N-nitrosoaniline (2) were measured using a differential scanning calorimeter. Simple eutectic behaviors for these systems were observed. The experimental results were correlated by means of original and modified NRTL, Wilson, and UNIQUAC equations. The root–mean–square deviations of the solubility temperatures for all measured data vary from 0.63 K to 3.73 K and depend on the particular model used. The best solubility correlation was obtained with the UNIQUAC model.

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Authors and Affiliations

  1. Ecole Militaire Polytechnique EMP, BP 17, Bordj–el-Bahri, Algiers, Algeria

    Djalal Trache & Kamel Khimeche

  2. Laboratoire de Thermodynamique et de Modélisation Moléculaire, Faculté de Chimie, USTHB, BP. 32 El-Alia, 16111 , Bab-Ezzouar, Algiers, Algeria

    Abdallah Dahmani

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  1. Djalal Trache
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  2. Kamel Khimeche
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  3. Abdallah Dahmani
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Correspondence to Kamel Khimeche.

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Trache, D., Khimeche, K. & Dahmani, A. Study of (Solid–Liquid) Phase Equilibria for Mixtures of Energetic Material Stabilizers and Prediction for Their Subsequent Performance. Int J Thermophys 34, 226–239 (2013). https://doi.org/10.1007/s10765-013-1404-4

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  • DOI: https://doi.org/10.1007/s10765-013-1404-4

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