Abstract
Fragments of Chelyabinsk LL5 No 1a and 2a, Kemer L4 and Ozerki L6 ordinary chondrites covered with the fusion crust were studied by X-ray diffraction (XRD) and Mössbauer spectroscopy. In addition, Kemer L4 and Ozerki L6 were studied by magnetization measurements. These results were analyzed for comparison of the bulk interior and the fusion crust in these meteorites. XRD showed the main and minor iron-bearing phases variations between both the bulk interior and the fusion crust in these meteorite fragments. Magnetization measurements of the bulk interior showed the magnetic phase transitions in chromite and hercynite in Ozerki L6 and Kemer L4 and different saturation magnetization moments for two meteorites as well as its decrease for the fusion crust from both fragments. Mössbauer spectra of the bulk interior and the fusion crust from Chelyabinsk LL5 No 1a and 2a, Kemer L4 and Ozerki L6 showed some differences in the numbers and contents of iron-bearing phases, small variations in the 57Fe hyperfine parameters in the same iron-bearing phases from different ordinary chondrites. Some differences in the Fe2+ occupations of the M1 and M2 sites in silicate crystals as well as variations in the temperatures of cation equilibrium distribution between these sites in olivine and orthopyroxene in the bulk interior were determined based on XRD and Mössbauer data.
Similar content being viewed by others
Data Availability
All data can be obtained from the corresponding author under request.
References
Rubin, A.E.: Mineralogy of meteorite groups. Meteorit. & Planet. Sci. 32, 231–247 (1997)
Rubin, A.E., Ma, C.: Meteoritic minerals and their origins. Chem. Erde. 77, 325–385 (2017)
Morozov, M., Brinkmann, C., Lottermoser, W., Tippelt, G., Amthauer, G., Kroll, H.: Octahedral cation partitioning in mg,Fe2+-olivine. Mössbauer spectroscopic study of synthetic (Mg0.5 Fe2 +0.5)2SiO4 (Fa50). Eur. J. Mineral. 17, 495–500 (2005)
Van Alboom, A., De Grave, E., Vandenberghe, R.E.: Study of the temperature dependence of the hyperfine parameters in two orthopyroxenes by 57Fe Mössbauer spectroscopy. Phys. Chem. Minerals. 20, 263–275 (1993)
Dyar, M.D., Klima, R.L., Fleagle, A., Peel, S.E.: Fundamental Mössbauer parameters of synthetic Ca-Mg-Fe pyroxenes. Am. Mineral. 98, 1172–1186 (2013)
Maksimova, A.A., Petrova, E.V., Chukin, A.V., Oshtrakh, M.I.: Fe2+ partitioning between the M1 and M2 sites in silicate crystals in some stony and stony-iron meteorites studied using X-ray diffraction and Mössbauer spectroscopy. J. Mol. Struct. 1216, 128391 (2020)
Oshtrakh, M.I., Maksimova, A.A., Chukin, A.V., Petrova, E.V., Jenniskens, P., Kuzmann, E., Grokhovsky, V.I., Homonnay, Z., Semionkin, V.A.: Variability of chelyabinsk meteoroid stones studied by Mössbauer spectroscopy and X-ray diffraction. Spectrochim. Acta, A. Mol. Biomol. Spectrosc. 219, 206–224 (2019)
Maksimova, A.A., Petrova, E.V., Chukin, A.V., Karabanalov, M.S., Nogueira, B.A., Fausto, R., Yesiltas, M., Felner, I., Oshtrakh, M.I.: Characterization of Kemer L4 meteorite using Raman spectroscopy, X-ray diffraction, magnetization measurements and Mössbauer spectroscopy. Spectrochim. Acta, A. Mol. Biomol. Spectrosc. 242, 118723 (2020)
Maksimova, A.A., Petrova, E.V., Chukin, A.V., Karabanalov, M.S., Felner, I., Gritsevich, M., Oshtrakh, M.I.: Characterization of the matrix and fusion crust of the recent meteorite fall ozerki L6. Meteorit. & Planet. Sci. 55, 231–244 (2020)
Oshtrakh, M.I., Semionkin, V.A.: Mössbauer spectroscopy with a high velocity resolution: advances in biomedical, pharmaceutical, cosmochemical and nanotechnological research. Spectrochim. Acta, A. Mol. Biomol. Spectrosc. 100, 78–87 (2013)
Oshtrakh, M.I., Semionkin, V.A.: Mössbauer spectroscopy with a high velocity resolution: principles and applications. In: Tuček J., Miglierini M. (eds.) Proceedings of the International Conference “Mössbauer Spectroscopy in Materials Science; AIP Conference Proceedings, vol. 1781, 020019. AIP Publishing, Melville, New York (2016)
Alenkina, I.V., Ushakov, M.V., Morais, P.C., Kalai Selvan, R., Kuzmann, E., Klencsár, Z., Felner, I., Homonnay, Z.: Oshtrakh M.I. Mössbauer spectroscopy with a high velocity resolution in the studies of nanomaterials. Nanomaterials. 12, 3748 (2022)
Maksimova, A.A., Klencsár, Z., Oshtrakh, M.I., Petrova, E.V., Grokhovsky, V.I., Kuzmann, E., Homonnay, Z., Semionkin, V.A.: Mössbauer parameters of ordinary chondrites influenced by the fit accuracy of the troilite component: An example of Chelyabinsk LL5 meteorite. Hyperfine Interact. 237, 33 (2016)
Maksimova, A.A., Oshtrakh, M.I., Petrova, E.V., Grokhovsky, V.I., Semionkin, V.A.: Comparison of iron-bearing minerals in ordinary chondrites from H, L and LL groups using Mössbauer spectroscopy with a high velocity resolution. Spectrochim. Acta, A. Mol. Biomol. Spectrosc. 172, 65–76 (2017)
Oshtrakh, M.I., Semionkin, V.A.: Testing of the velocity driving system in Mössbauer spectrometers using reference absorbers. Hyperfine Interact. 242, 28 (2021)
Gattacceca, J., Rochette, P., Lagroix, F., Mathé, P.-E., Zanda, B.: Low temperature magnetic transition of chromite in ordinary chondrites. Geophys. Res. Lett. 38, L10203 (2011)
Klemme, S., van Miltenburg, J.C.: Thermodynamic properties of hercynite (FeAl2O4) based on adiabatic calorimetry at low temperatures. Am. Mineral. 88, 68–72 (2003)
Kruse, O.: Mössbauer and X-ray study of the effects of vacancy concentration in synthetic hexagonal pyrrhotites. Am. Mineral. 75, 755–763 (1990)
Maksimova, A.A., Oshtrakh, M.I.: Applications of Mössbauer spectroscopy in meteoritical and planetary science, part I: Undifferentiated meteorites. Minerals. 11, 612 (2021)
Acknowledgements
This work was supported by the Ministry of Science and Higher Education of the Russian Federation, project № FEUZ-2023-0013. The research funding for M.I.O. and E.V.P. from the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program) is gratefully acknowledged.
Author information
Authors and Affiliations
Contributions
M.I.O. wrote the main manuscript text, M.I.O., A.A.M., E.V.P., A.V.C. and I.F. did all measurements. All authors reviewed the manuscript.
Corresponding author
Ethics declarations
Ethical approval
Not applicable.
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Oshtrakh, M.I., Maksimova, A.A., Petrova, E.V. et al. Comparison of bulk interior and fusion crust of Chelyabinsk LL5, Ozerki L6 and Kemer L4 ordinary chondrite fragments using X-ray diffraction and Mössbauer spectroscopy. Hyperfine Interact 244, 22 (2023). https://doi.org/10.1007/s10751-023-01830-9
Accepted:
Published:
DOI: https://doi.org/10.1007/s10751-023-01830-9