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Application of synchrotron-radiation-based Mössbauer spectroscopy to 193Ir 73 keV transition

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Abstract

Synchrotron-radiation-based (SR-based) Mössbauer spectroscopy was applied to 193Ir 73 keV transition. Measuring the spectra of Ir metal and IrO2 at 7 K was performed to evaluate the spectrometer employing He-closed-cycle cryostats. The SR-based Mössbauer spectroscopy on 193Ir 73 keV Mössbauer transition was applied to investigate the physical properties of an intermediate valence iridium oxide Ca5Ir3O12. Efficiency of measuring spectra on operation modes of a synchrotron radiation facility was also discussed.

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Acknowledgements

The authors appreciate Hisao Kobayashi for his technical assistance. 193Ir SR-based Mössbauer spectroscopy experiments were performed under the approval of JASRI (Proposal No. 2020A2014, 2020A2078). This work is financially supported by JSPS KAKENHI (Grant Nos. JP18H04327 (J-Physics), JP21H00157(high-entropy), JP19H04408).

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Authors and Affiliations

  1. Japan Synchrotron Radiation Research Institute (JASRI), SPring-8, Sayo, Hyogo, 679-5198, Japan

    Satoshi Tsutsui & Yoshitaka Yoda

  2. Institute of Quantum Beam Science, Graduate School of Science and Engineering, Ibaraki University, Hitachi, Ibaraki, 316-8511, Japan

    Satoshi Tsutsui

  3. Graduate School of Engineering, Kyushu Institute of Technology, Kita-Kyushu, Fukuoka, 804-8550, Japan

    Hiroki Hanate & Kazuyuki Matsuhira

  4. Faculty of Science and Technology, Hirosaki University, Hirosaki, Aomori, 036-8152, Japan

    Ryo Masuda

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  1. Satoshi Tsutsui
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  2. Hiroki Hanate
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  3. Yoshitaka Yoda
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  5. Kazuyuki Matsuhira
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Correspondence to Satoshi Tsutsui.

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This article is part of the Topical Collection on Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2021), 5-10 September 2021, Brasov, Romania

Edited by Victor Kuncser.

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Tsutsui, S., Hanate, H., Yoda, Y. et al. Application of synchrotron-radiation-based Mössbauer spectroscopy to 193Ir 73 keV transition. Hyperfine Interact 242, 21 (2021). https://doi.org/10.1007/s10751-021-01743-5

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