In this paper, the physico chemical properties of Fe–based amorphous alloys containing critical raw materials (CRM) were investigated in order to reuse them for photocatalytic degradation of azo dyes. The iron-based metallic glasses were prepared by melt spinning method. Their chemical composition is: Fe67B14Co18Si, Fe78B15Mo2Si5 and Fe40B16Ni40Mo4. Characterization of the ribbons was done using combination of analytical methods. Studied materials were heated in inert atmosphere and in air at temperature of 1000 °C. Crystallization processes of investigated Fe–based amorphous alloys depending on their chemical composition were registered using thermal analysis. The changes of material phase composition and crystallinity degree were studied using powder X-ray diffraction (XRD) and Mössbauer spectroscopy (MS). The thermal treatment in inert atmosphere above the crystallization temperature of studied amorphous alloys result in rearrangement of iron neighbours and formation of multiphase crystalline structure, which strongly depends on the additive elements (Co, Ni, Mo). Heating of ribbons in air affects significantly the kinetic of crystallization and registered products in comparison to annealing in inert (argon) atmosphere. Investigation of thermal stability of ribbon metallic glasses and formation of different intermediate and product compounds is very important for practical application of damaged amorphous alloys, their further reuse and recycling.
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Gutfleisch, O., Willard, M.A., Brück, E., Chen, C.H., Sankar, S.G., Liu, J.P.: Magnetic materials and devices for the 21st century: stronger, lighter, and more energy efficient. Adv. Mater. 23, 821–842 (2011)
Liu Y., Sellmyer D.J., Shindo D.: Handbook of advanced magnetic materials. Springer US (2006)
Idzikowski, B., Svec, P., Miglierini, M.: Properties and applications of nanocrystalline alloys from amorphous precursors. Series II: Mathematics, Physics and Chemistry, vol. 184, NATO Science Series, Kluwer Academic Publishers (2005)
List of critical raw materials for the EU https://ec.europa.eu/growth/sectors/raw-materials/specific-interest/critical_en
Directorate-General for Environment (European Commission): LIFE and the Circular economy, 2017-05-18; https://publications.europa.eu/en/publication-detail/-/publication/ac9eab4b-4045-11e7-a9b0-01aa75ed71a1
Grenèche, J.M., Miglierini, M.: Mössbauer spectrometry applied to iron-based nanocrystalline alloys I.: high temperature studies. In: Miglierini, M., Petridis, D. (eds.) Mössbauer Spectroscopy in Materials Science, pp. 243–256. Kluwer Academic Publishers, Dordrecht (1999)
Miglierini M., Grenèche JM.: Mössbauer Spectrometry Applied to Iron-Based Nanocrystalline Alloys II. In: Miglierini M., Petridis D. (eds) Mössbauer Spectroscopy in Materials Science. NATO Science Series (3. High Technology), (1999) vol 66. Springer, Dordrecht, pp. 257–272
Grenèche JM., Varret F.: Independence of magnetic texture and hyperfine data from Mössbauer spectra of a ferromagnetic metallic glass. Solid State Commun., 54(11), 985–989 (1985)
Prasad, B., Bhatnagar, A., Jagannathan, R.: Amorphous to crystalline transformation of Fe81B13.5Si3.5C2. Appl. Phys. 54, 2019–2024 (1983)
Zhao, L., Li, C., Hao, Z., Liu, X., Liao, X., Zhang, J., Su, K., Li, L., Yu, H., Greneche, J.M., Jin, J., Liu, Z.: Influences of element segregation on the magnetic properties in nanocrystalline Nd-Ce-Fe-B alloys. Materials Characterization 148, 208–213 (2019)
Minić, D.M., Minić, D.M., Žák, T., Roupcová, P., David, B.: Structural transformations of Fe81B13Si4C2 amorphous alloy induced by heating. J. Magn. Magn. Mater. 323, 400–404 (2011)
Sun, X., Cabral-Prieto, A., Yacaman, M.J., Reyes-Gasga, J., Hernandez-Reyes, R., Morales, A., Sun, W.: Nanocrystallization behavior and magnetic properties of amorphous Fe78Si9B13 ribbons Physica B. 291, 173–179 (2000)
Pratar, A., Lilly, T., Rao, S., Patel, K., Chawda, M.: Kinetics of crystallization of a Fe-based multicomponent amorphous alloy. Bull. Mater. Sci. Indian Acad. Sci. 32, 527–529 (2009)
Raja, V., Kishore, S., Ranganathan, S.: Crystallization behaviour of Metglas 2826 MB (Fe40Ni38Mo4B18). Bull. Mater. Sci. Indian Acad. Sci. 9, 207–217 (1987)
Saiseng, S., Winotai, P., Nilpairuch, S., Limsuwan, P., Tang, I.M.: Nanocrystallization in amorphous Fe40Ni40(Si+B)19Mo1–2 ribbons. J. Magn. Magn. Mater. 278, 172–178 (2004)
Cornell, R., Schwertmann, U.: The Iron oxides: structure, properties, reactions, occurrences and uses. Weinheim VCH. New York (2006)
Gotić, M., Musić, S.: Mössbauer, FT-IR and FE SEM investigation of iron oxides precipitated from FeSO4 solutions. J. Mol. Struct. 834–836, 445–453 (2007)
Niemantsverdriet, J.W., Van der Kraan, A.M., Delgass, W.N., Vannice, M.A.: Small-particle effects in Mössbauer spectra of a carbon-supported iron catalyst. J. Phys. Chem. 89, 67–72 (1985)
The authors gratefully acknowledge the financial support of the Bulgarian National Science Fund at the Ministry of Education and Science - Project № DCOST 01/22/ 2017. This article is based on work from COST Action CA 15102 “Solutions for Critical Raw Materials under Extreme Conditions (CRM-EXTREME)”, supported by COST (European Cooperation in Science and Technology).
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This article is part of the Topical Collection on Proceedings of the 5th Mediterranean Conference on the Applications of the Mössbauer Effect (MECAME 2019) and 41st Workshop of the French-speaking Group of Mössbauer Spectroscopy (GFSM 2019), Montpellier, France, 19-23 May 2019
Edited by Pierre-Emmanuel Lippens, Yann Garcia, Moulay-Tahar Sougrati and Mira Ristic (†)
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Cherkezova-Zheleva, Z., Paneva, D., Petkova, V. et al. Reuse of Fe-based amorphous alloys containing CRM: study on their temperature behavior. Hyperfine Interact 241, 14 (2020). https://doi.org/10.1007/s10751-019-1684-6
- Fe-based amorphous alloys
- Critical raw materials (CRM)
- 57Fe Mössbauer spectroscopy
- Thermal analysis