Mössbauer spectroscopy study of Y-type Hexaferrite (Ba2Co2Fe12O22) prepared by the co-precipitation method

Abstract

In this work we report the results of structural and Mössbauer spectroscopy studies for Ba2Co2Fe12O22 samples prepared by coprecipitation following two different synthesis routes: route A (pH = 10, NaOH + Na2CO3 added dropwise), and route B (pH = 14, NaOH + Na2CO3 added one shot). The resulting powders were sintered for 4 h at different temperatures (700 °C to 1100 °C in steps of 100 °C). The sintered powders were characterized by x-ray diffraction (XRD) and room temperature Mössbauer spectroscopy. XRD and Mössbauer results of the sample prepared by route A and sintered at 700 °C revealed formation of spinel phases (CoFe2O4 and/or Fe3O4), BaCO3 and BaM-type phase. The Co2Y phase developed in the samples sintered at 800 °C and 900 °C with spinel species as impurities, and single (pure) Co2Y phase was obtained at higher temperatures. On contrast, XRD patterns and the Mössbauer spectra for the samples prepared by route B showed different results, where the sample sintered at 700 °C consisted of only spinel phases. The Co2Y phase developed at higher temperatures, coexisting with significant amounts of other phases.

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Acknowledgements

The authers acknowledge the contribution of Prof. I. Bsoul at Al al-Bayt University in the Rietveld refinement analysis. The Financial support of the Deanship of Scientific Research and Graduate Studies at Yarmouk University is acknowledged. A-F. Lehlooh appreciates the full support of Yarmouk University to attend ICAME 2019 in Dalian.

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Correspondence to Abdel-Fatah Lehlooh.

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This article is part of the Topical Collection on Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME2019), 1-6 September 2019, Dalian, China

Edited by Tao Zhang, Junhu Wang and Xiaodong Wang

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Lehlooh, AF., Alghazo, R., Rawwagah, F. et al. Mössbauer spectroscopy study of Y-type Hexaferrite (Ba2Co2Fe12O22) prepared by the co-precipitation method. Hyperfine Interact 241, 12 (2020). https://doi.org/10.1007/s10751-019-1676-6

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Keywords

  • Ba2Co2Fe12O22
  • Y-type hexaferrite
  • X-ray diffraction
  • Coprecipitation
  • Mössbauer spectroscopy
  • Sintering