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In-beam Mössbauer spectra for 57Mn implanted sulfur hexafluoride

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Abstract

To investigate the interactions of 57Fe atoms with sulfur hexafluoride SF6 molecules, in-beam Mössbauer spectra were measured for 57Mn implanted SF6 at 9 K and 65 K. Isolated 57Fe atoms or ions produced by β-decay were not trapped within the SF6 matrix. At 9 K, monomeric FeF2 and FeF3 molecules were produced by reaction of 57Fe with F atoms released by decomposition of the SF6 molecules. When the temperature of the SF6 solid was increased to 65 K, FeF4 was formed in addition to FeF2 and FeF3. Density functional calculations were performed to confirm the assignments of the candidate species identified in the Mössbauer spectra.

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Authors and Affiliations

  1. Department of Chemistry, Tokyo University of Science, Tokyo, Japan

    Yasuhiro Yamada & Yukiko Sato

  2. Graduate School of Engineering Science, University of Electro-Communications, Chofu, Japan

    Yoshio Kobayashi, Takatoshi Ando, Noriko Takahama, Kanako Some & Masami Sato

  3. Nishina Center for Accelerator-Based Science, RIKEN, Tokyo, Japan

    Yoshio Kobayashi & Takashi Nagatomo

  4. Graduate School of Science, Osaka University, Suita, Japan

    Mototugu Mihara

  5. College of Liberal Arts, International Christian University, Mitaka, Japan

    M. Kenya Kubo & Junji Kobayashi

  6. Institute of Science and Engineering, Kanazawa University, Kanazawa, Japan

    Wataru Sato

  7. Faculty of Pharmaceutical Sciences, Hokuriku University, Kanazawa, Kanazawa, Japan

    Jun Miyazaki

  8. Department of Basic Science, The University of Tokyo, Tokyo, Japan

    Atsushi Okazawa

  9. National Institute of Radiological Sciences, Chiba, Japan

    Shinji Sato & Atsushi Kitagawa

Authors
  1. Yasuhiro Yamada
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  2. Yukiko Sato
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  3. Yoshio Kobayashi
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  4. Takatoshi Ando
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  5. Noriko Takahama
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  6. Kanako Some
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  7. Masami Sato
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  8. Mototugu Mihara
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  9. M. Kenya Kubo
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  10. Wataru Sato
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  11. Jun Miyazaki
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  12. Takashi Nagatomo
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  13. Junji Kobayashi
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  14. Atsushi Okazawa
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  15. Shinji Sato
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  16. Atsushi Kitagawa
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Correspondence to Yasuhiro Yamada.

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This article is part of the Topical Collection on Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME2019), 1-6 September 2019, Dalian, China

Edited by Tao Zhang, Junhu Wang and Xiaodong Wang

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Yamada, Y., Sato, Y., Kobayashi, Y. et al. In-beam Mössbauer spectra for 57Mn implanted sulfur hexafluoride. Hyperfine Interact 241, 15 (2020). https://doi.org/10.1007/s10751-019-1655-y

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  • DOI: https://doi.org/10.1007/s10751-019-1655-y

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