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Hyperfine Interactions

, 237:92 | Cite as

Klimt artwork (Part II): material investigation by backscattering Fe-57 Mössbauer- and Raman- spectroscopy, SEM and p-XRF

  • B. F. O. Costa
  • R. Lehmann
  • D. Wengerowsky
  • M. Blumers
  • A. Sansano
  • F. Rull
  • H.-J. Schmidt
  • F. Dencker
  • A. Niebur
  • G. Klingelhöfer
  • R. Sindelar
  • F. RenzEmail author
Article
Part of the following topical collections:
  1. Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2015), Hamburg, Germany, 13-18 September 2015

Abstract

In a rediscovered Klimt-artwork “Trompetender Putto” material tests have been conducted. We report studies on different points of the painting. The spots are of different colors, mainly taken in spots of the painting not restaurated. MIMOS II Fe-57 Mössbauer spectroscopy revealed mainly haematite and nano particle oxides in red and red/brown colors. Brown colors also contain crystallized goethite. In brown/ochre colors the same pigments as in brown colors are observed, but there is less quantity of goethite and more quantity of haematite. The green colors show Fe-rich clays, like celadonite or glauconite and or lepidocrocite as main component. Raman spectroscopy revealed cinnabar in red colors of the Scarf; and massicot in brown/ochre points, i.e. in the Left Wing of the “Putto”. With scanning electron microscopy, various layers of the original and of overpainting could be recognized. The investigations of sample 1 show three layers of colored materials, which were identified as zinc-white, cinnabar and galena as well as carbon compounds. In sample 2 four layers could be detected. These are identified (bottom to top) as gypsum and lead-white (layer 1), zinc-white (layer 2), lead-white and cinnabar (layer 3) and titanium-white (layer 4). The elementary composition was examined with the portable X-ray-fluorescence analysis for qualitative manner at different points.

Keywords

“Trompetender Putto” Klimt Mössbauer spectroscopy Raman spectroscopy Scaning electron microscopy X-ray fluorescence analysis Pigments 

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Copyright information

© Springer International Publishing Switzerland 2016

Authors and Affiliations

  • B. F. O. Costa
    • 1
  • R. Lehmann
    • 2
  • D. Wengerowsky
    • 2
  • M. Blumers
    • 3
  • A. Sansano
    • 4
  • F. Rull
    • 4
  • H.-J. Schmidt
    • 2
  • F. Dencker
    • 5
  • A. Niebur
    • 6
  • G. Klingelhöfer
    • 3
  • R. Sindelar
    • 5
  • F. Renz
    • 2
    Email author
  1. 1.CFisUC, Physics DepartmentUniversity of CoimbraCoimbraPortugal
  2. 2.Institut für Anorganische ChemieLeibniz Universität HannoverHannoverGermany
  3. 3.Institut für Anorganische Chemie und Analytische ChemieJoh. Gutenberg-Universität MainzMainzGermany
  4. 4.Unidad Asociada UVA-CSIC Centro de AstrobiologiaValladolidSpain
  5. 5.Hochschule Hannover, Fakultät II-Maschinenbau und BioverfahrenstechnikHannoverGermany
  6. 6.Technische Universität Dresden, Institut für Physikalische ChemieDresdenGermany

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