Abstract
The room temperature Mössbauer spectra of 57Fe were measured for nanocrystalline iron-based solid solutions Fe 1−x Re x , prepared by mechanical alloying with x in the range 0.01 ≤ x ≤ 0.04. The obtained data were analysed in terms of the binding energy E b between two rhenium atoms in the Fe-Re system. The extrapolated value of E b for x = 0 was used for computation of enthalpy of solution of rhenium in iron. The result was compared with that resulting from the cellular atomic model of alloys by Miedema as well as with value, derived from proper data for Fe-Re solid solutions obtained by melting in an arc furnace. From the comparison it follows that our findings are in agreement with the Miedema’s model predictions and previous Mössbauer studies.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Takeuchi, J., Katsube, H., Hiromitsu, I., Ito, T.: Magnetic properties of mechanically alloyed amorphous Fe-M-Zr (M = Mn, Co, Ni, Ce, Dy, Er). J. Magn. Magn. Mater. 140-144, 303–304 (1995)
Froesa, F.H., Suryanarayana, C., Russellb, K., Li, C.-G.: Synthesis of intermetallics by mechanical alloying. Mater. Sci. Eng. A 192(/193), 612–623 (1995)
Suryanarayana, C.: Mechanical alloying and milling. Prog. Mater. Sci. 46, 1–184 (2001)
Shen, T.D., Xin, S.W., Sun, B.R.: Influence of annealing on the mechanical property of iron- and nickel-based nanocrystalline alloys. Mater. Sci. Eng. A 627, 139–144 (2015)
Karolus, M., Jartych, E., Oleszak, D.: Structure and magnetic properties of nanocrystalline Fe-Mo alloys prepared by mechanosynthesis. Acta Phys. Pol. A 102, 253–258 (2001)
Konieczny, R., Idczak, R.: Atomic short-range order in mechanically synthesized iron based Fe-Zn alloys studied by 57Fe Mössbauer spectroscopy. Nukleonika 60, 69–73 (2015)
Idczak, R., Konieczny, R., Chojcan, J.: Short-range order in iron alloys studied by 57Fe Mössbauer spectroscopy. Solid State Commun. 159, 22–25 (2013)
Konieczny, R., Idczak, R., Chojcan, J.: Mössbauer studies of interactions between osmium atoms dissolved in iron. Nukleonika 60, 75–79 (2015)
Konieczny, R., Idczak, R., Elsner, J., Chojcan, J.: An enthalpy of solution of platinum in iron studied by 57Fe Mössbauer spectroscopy. Hyperfine Interact. 206, 119 (2012)
Idczak, R., Konieczny, R., Chojcan, J.: An enthalpy of solution of chromium in iron studied with 57Fe Mössbauer spectroscopy. Physica B 407, 2078–2081 (2012)
Idczak, R., Konieczny, R., Konieczna, ż., Chojcan, J.: An Enthalpy of Solution of Cobalt and Nickel in Iron Studied with 57Fe Mössbauer Spectroscopy. Acta Phys. Pol. A 119, 37–40 (2011)
Vincze, I., Campbell, I.A.: Mössbauer measurements in iron based alloys with transition metals. J. Phys. F 3, 647 (1973)
Królas, K.: Correlation between impurity binding energies and heat of formation of alloys. Phys. Lett. A 85, 107 (1981)
Miedema, A.R.: Energy effects and charge transfer in metal physics, modeling in real space. Physica B 182, 1 (1992)
Bonny, G., Pasianot, R.C., Malerba, L., Caro, A., Olsson, P., Lavrentiev, M.Y.: Numerical predictions of thermodynamic properties of iron-chromium alloys using semi-empirical cohesive models: the state of the art. J. Nucl. Mater. 385, 268 (2009)
Boom, R., De Boer, F.R., Niessen, A.K., Miedema, A.R.: Enthalpies of formation of liquid and solid binary alloys based on 3d metals. Physica 115B, 285 (1983)
Lejaeghere, K., Cottenier, S., Claessens, S., Waroquier, M., Van Speybroeck, V.: Assessment of a low-cost protocol for an ab inito based prediction of the mixing enthalpy at elevated temperatures: the Fe-Mo system. Phys. Rev. B 83, 184201 (2011)
Hultgren, R., Desai, P.D., Hawkins, D.T., Gleiser, M., Kelley, K.K.: Selected Values of Thermodynamic Properties of Binary Alloys. American Society for Metals, Metals Park, Ohio (1973)
Swartzendruber, L.J., Itkin, V.P., Alcock, C.B.: Phase diagrams of binary iron alloys. In: Okamoto, H. (ed.) Materials Information Society. Materials Park, Ohio (1993)
Wertheim, G.K., Jaccarino, V., Wernick, J.H., Buchanan, D.N.E.: Range of the exchange interaction in iron alloys. Phys. Rev. Lett. 12, 24–27 (1964)
Sauer, W.E., Reynik, R.J.: Electronic and magnetic structure of dilute Iron-Base alloys. J. Appl. Phys. 42, 1604–1605 (1971)
Ovchinnikov, V.V.: Mössbauer Analysis of the Atomic and Magnetic Structure of Alloys. Cambridge International Science Publishing, Cambridge (2006)
Konieczny, R., Idczak, R., Szarypo, W., Chojcan, J.: An enthalpy of solution of rhenium in iron studied by 57Fe Mössbauer spectroscopy. Hyperfine Interact. 206, 135 (2012)
Dubiel, S.M.: Rhenium-induced changes in the electronic structure of iron. J. Magn. Magn. Mater. 69, 206–214 (1987)
Błachowski, A., Wdowik, U.D.: Transition metal impurity effect on charge and spin density in iron: Ab initio calculations and comparison with Mössbauer data. J. Phys. Chem. Solids 73, 317–323 (2012)
Chojcan, J.: Interaction between impurity atoms of 3d transition metals dissolved in iron. J. Alloys Compd. 264, 50 (1998)
Hrynkiewicz, A.Z., Królas, K.: Formation of two-impurity complex in dilute alloys observed through perturbed angular correlation of γ rays. Phys. Rev. B 28, 1864–1869 (1983)
Author information
Authors and Affiliations
Corresponding author
Additional information
This article is part of the Topical Collection on Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2015), Hamburg, Germany, 13-18 September 2015.
Rights and permissions
Open Access This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
About this article
Cite this article
Konieczny, R., Idczak, R. Mössbauer study of Fe-Re alloys prepared by mechanical alloying. Hyperfine Interact 237, 12 (2016). https://doi.org/10.1007/s10751-016-1232-6
Published:
DOI: https://doi.org/10.1007/s10751-016-1232-6