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Mössbauer spectroscopic study of FeII-doped sulphonated poly(ether-urethane)—styrene-acrylate copolymer

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Abstract

Thermoplastic linear ionomer based on sulphonated poly(ether-urethane)—styrene-acrylate copolymer, doped with natural Fe2 + , was studied by Mössbauer spectroscopy at T = 78 and 290 K to monitor the chemical state of Fe species. The Fe2 +  added to aqueous suspension of the system was only partly oxidised in the course of polymer film preparation and drying in air. The oxidised part comprised a magnetic phase (~19 % of total Fe both at T = 78 and 298 K) and a quadrupole doublet (~40 %), while FeII (over 40 %) stabilised in two types of microenvironments.

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Authors and Affiliations

  1. Institute of Biochemistry and Physiology of Plants and Microorganisms, Russian Academy of Sciences, Saratov, 410049, Russia

    A. A. Kamnev

  2. Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kyiv, 02160, Ukraine

    O. P. Grigoryeva & A. M. Fainleib

  3. Institute of Chemistry, Eötvös Loránd University, Budapest, 1117, Hungary

    E. Kuzmann

Authors
  1. A. A. Kamnev
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  2. O. P. Grigoryeva
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  3. A. M. Fainleib
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  4. E. Kuzmann
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Correspondence to E. Kuzmann.

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Kamnev, A.A., Grigoryeva, O.P., Fainleib, A.M. et al. Mössbauer spectroscopic study of FeII-doped sulphonated poly(ether-urethane)—styrene-acrylate copolymer. Hyperfine Interact 218, 67–70 (2013). https://doi.org/10.1007/s10751-012-0659-7

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  • DOI: https://doi.org/10.1007/s10751-012-0659-7

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