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2D iron(II) spin crossover complex with 3,5-lutidine

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Abstract

2D coordination polymer iron(II) spin crossover complexes containing 3,5-lutidine with host framework Fe(3,5-lutidine)2Ni(CN)4were synthesized. Their spin crossover properties were studied by temperature dependent 57Fe Mössbauer spectroscopy. Materials show gradual incomplete spin crossover with distinct thermochromism, while only 25 % of iron(II) ions are switched to the low spin state at 80 K, as determined by a detailed 57Fe Mössbauer study.

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References

  1. Gütlich, P., Goodwin, H.A. (eds.): Spin crossover in transition metal compounds, topics in current chemistry, vols. 233–235. Springer Verlag, Berlin (2004)

    Google Scholar 

  2. Garcia, Y., Niel, V., Muñoz, M.C., Real, J.A.: Top. Curr. Chem. 233, 229 (2004)

    Article  Google Scholar 

  3. Kitazawa, T., Gomi, Y., Takahashi, M., Takeda, M., Enomoto, M., Miyazaki, A., Enoki, T.: J. Mater. Chem. 6, 119 (1996)

    Article  Google Scholar 

  4. Sato, T., Ambe, F., Kitazawa, T., Sano, H., Takeda, M.: Chem. Lett. 1287 (1997)

  5. Kitazawa, T., Takahashi, Mi., Takahashi, Ma., Enomoto, M., Miyazaki, A., Enoki, T., Takeda, M.: J. Radio. Nucl. Chem. 239, 285 (1999)

    Article  Google Scholar 

  6. Molnár, G., Guillon, T., Moussa, N.O., Rechignat, L., Kitazawa, T., Nardone, M., Bousseksou, A.: Chem. Phys. Lett. 423, 152 (2006)

    Article  ADS  Google Scholar 

  7. Martínez, V., Gaspar, A.B., Muñoz, M.C., Bukin, G.V., Levchenko, G., Real, J.A.: Chem. Eur. J. 15, 10960 (2009)

    Article  Google Scholar 

  8. Martínez, V., Boldog, I., Gaspar, A.B., Ksenofontov, V., Bhattacharjee, A., Gütlich, P., Real, J.A.: Chem. Mater. 22, 4271 (2010)

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba, 274-8510, Japan

    Takafumi Kitazawa, Miwa Takahashi & Takeshi Kawasaki

  2. Research Centre for Materials with Integrated Properties, Toho University, 2-2-1 Miyama, Funabashi, Chiba, 274-8510, Japan

    Takafumi Kitazawa

Authors
  1. Takafumi Kitazawa
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  2. Miwa Takahashi
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  3. Takeshi Kawasaki
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Correspondence to Takafumi Kitazawa.

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Kitazawa, T., Takahashi, M. & Kawasaki, T. 2D iron(II) spin crossover complex with 3,5-lutidine. Hyperfine Interact 218, 133–138 (2013). https://doi.org/10.1007/s10751-012-0649-9

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  • DOI: https://doi.org/10.1007/s10751-012-0649-9

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