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Mössbauer study of magnetism in FeII − III (oxy-)hydroxycarbonate green rusts; ferrimagnetism of FeII − III hydroxycarbonate

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Abstract

FeII − III hydroxycarbonate Fe\(^{\rm II}_{4}\)Fe\(^{\rm III}_{2}\)(OH)12CO3, green rust GR(CO\(_{3}^{2-})\), reveals a ferrimagnetic behaviour. Moments that lie within two-dimensional cation layers are parallel for same species and antiparallel between FeII and FeIII. Respective ordering temperatures are 5.2 and 7 K. A sextet with distribution from 350 to 580 kOe for FeIII and an octet reflecting a mixture of states with field of 130 kOe and quadrupole splitting of −3.0 mm s − 1 for FeII are observed at 1.4 K. Ferric oxyhydroxycarbonate Fe\(^{\rm III}_{6}\)O12H8CO3 is ferromagnetic and displays at 4 K a sextet with field between 400 and 500 kOe (maximum at 480 kOe) and transition at 80 K. GR(CO\(_{3}^{2-})\) deprotonation gives magnetic domains with compositions at x = 1/3, 2/3 and 1 due to long range order.

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Authors and Affiliations

  1. Laboratoire de Chimie Physique et Microbiologie pour l’Environnement, UMR 7564 CNRS–Université Henri Poincaré, Equipe Microbiologie, Physique and Département Matériaux et Structures, ESSTIN, 405 rue de Vandœuvre, 54600, Villers-lès-Nancy, France

    B. Rusch, J.-M. R. Génin, Ch. Ruby & M. Abdelmoula

  2. DSM/DRECAM, Service de Physique de l’Etat Condensé, Centre CEA de Saclay, Orme des Merisiers, 91191, Gif sur Yvette, France

    P. Bonville

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  1. B. Rusch
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  2. J.-M. R. Génin
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  3. Ch. Ruby
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  4. M. Abdelmoula
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  5. P. Bonville
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Correspondence to J.-M. R. Génin.

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Rusch, B., Génin, JM.R., Ruby, C. et al. Mössbauer study of magnetism in FeII − III (oxy-)hydroxycarbonate green rusts; ferrimagnetism of FeII − III hydroxycarbonate. Hyperfine Interact 187, 7–12 (2008). https://doi.org/10.1007/s10751-008-9862-y

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  • DOI: https://doi.org/10.1007/s10751-008-9862-y

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