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Formation of DX-centers in indium doped CdTe

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Abstract

In CdTe, the achievable n-type doping is limited by the formation of DX-centers. A characteristic feature of DX-centers is the ‘persistent photoconductivity (PPC)’ which is created by illumination at low temperatures and caused by a metastable state of the DX-center. The DX-center and the PPC effect in n-type CdTe are theoretically explained by the ‘large lattice relaxation model’. PAC measurements on In doped CdTe using 111In/111Cd and, in addition, resistivity measurements on the same samples have been performed. Below 150 K, the samples showed a PPC effect that was accompanied by an increase of about 20% of the carrier concentration. This effect is not accompanied by any changes of the observed EFG. Possible explanations of the EFG observed, originally assigned to the DX-center, will be discussed. Finally, first reports on the investigation of DX-centers in CdTe using the radioactive isotope 117Cd decaying to 117In are presented.

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References

  1. Desnica, U.V.: Doping limits in II-VI compounds-challenges, problems and solutions. Prog. Cryst. Growth Charact. 36, 291–357 (1998)

    Article  Google Scholar 

  2. Lang, D.V., Logan, R.A., Jaros, M.: Trapping characteristics and a donor-complex (DX) model for the persistent-photoconductivity trapping center in Te-doped AlxGa1−xAs. Phys. Rev. B 19, 1015–1030 (1979) 193

    Article  ADS  Google Scholar 

  3. Mooney, P.M.: Deep donor levels (DX centers) in III-V semiconductor. J. Appl. Phys. 67, R1–R26 (1990)

    Article  ADS  Google Scholar 

  4. Burkey, B.C., Khosla, R.P., Fischer, J.R., Losee, D.L.: Persistent photoconductivity in donor-doped Cd1−xZnxTe. J. Appl. Phys. 47, 1095–1102 (1976)

    Article  ADS  Google Scholar 

  5. Kachaturyan, K., Kaminska, M., Weber, E.R., Becla, P., Street, R.A.: Lattice relaxation of DX-like donors in ZnxCd1−xTe. Phys. Rev. B 40, 6304–6310 (1989)

    Article  ADS  Google Scholar 

  6. Han, J., Ringle, M.D., Fan, Y., Gunshor, R.L., Nurmikko, A.V.: D (donor) X center behavior for holes implied from observation of metastable acceptor states. Appl. Phys. Lett. 65, 3230 (1994)

    Article  ADS  Google Scholar 

  7. Thio, T., Bennet, J.W., Becla, P.: Deep donors in Cd1−xZnxTe:Cl. Phys. Rev. B 54, 1754–1758 (1996)

    Article  ADS  Google Scholar 

  8. Park, C.H., Chadi, D.J.: First-principles study of DX centers in CdTe, ZnTe, and CdxZn1−xTe alloys. Phys. Rev. B 52, 11884–11890 (1995)

    Article  ADS  Google Scholar 

  9. Park, C.H., Chadi, D.J.: Microscopic structure of DX centers of column III and VII impurities in CdTe. Appl. Phys. Lett. 66, 3167–3169 (1995)

    Article  ADS  Google Scholar 

  10. Bassani, F., Tatarenko, S., Saminadayar, K., Magnea, N., Cox, F.L.T., Tardot, A., Grattepain, C.: Indium doping of CdTe and Cd1−xZnxTe by molecular-beam epitaxy: uniformly and planar-doped layers, quantum wells, and superlattices. J. Appl. Phys. 72, 2927–2940 (1992)

    Article  ADS  Google Scholar 

  11. Espinosa, F.J., Mustre de Leon, J., Conradson, S.D., Peña, J.L., Zapata-Torres, M.: Observation of a photoinduced lattice relaxation in CdTe:In. Phys. Rev. Lett. 83, 3446–3449 (1999)

    Article  ADS  Google Scholar 

  12. Filz, T., Hamann, J., Müller, R., Ostheimer, V., Wolf, H., Wichert, T.: MOCVD grown CdTe investigated by photoluminescence and PAC. J. Cryst. Growth 159, 68–71 (1996)

    Article  ADS  Google Scholar 

  13. van der Pauw, L.J.: Method of measuring specific resistivity and hall effect of discs of arbitrary shape. Philips Res. Rep. 13, 1–9 (1958)

    Google Scholar 

  14. Firestone, R.B., Shirley, V.S. (eds.): Table of Isotopes, 8th edn. Wiley, New York (1996)

    Google Scholar 

  15. Lany, S., Wolf, H., Wichert, T.: DX-centers in CdTe and ZnTe observed by locally sensitive probe atoms. Mater. Res. Soc. Symp. Proc. 763, B1.3 (2003)

    Google Scholar 

  16. Lany, S., Wolf, H., Wichert, T.: Density functional theory calculations establish the experimental evidence of the DX center atomic structure in CdTe. Phys. Rev. Lett. 92, 225504 (2004)

    Article  ADS  Google Scholar 

  17. Christiansen, J., Heubes, P., Keitel, R., Klinger, W., Loeffler, W., Sandner, W., Witthuhn, W.: Temperature dependence of the electric field gradient in noncubic metals. Z. Physik B 24, 177–187 (1976)

    Article  ADS  Google Scholar 

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Türker, M., Kronenberg, J., Deicher, M. et al. Formation of DX-centers in indium doped CdTe. Hyperfine Interact 177, 103–110 (2007). https://doi.org/10.1007/s10751-008-9666-0

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  • DOI: https://doi.org/10.1007/s10751-008-9666-0

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