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Zero-field splittings of NQR spectra for bismuth(III) oxy compounds revealed by quadrupole spin echo envelopes

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Abstract

Local magnetic fields up to 250 G were earlier found by measuring the NQI parameters in bismuth(III) oxy compounds conventionally considered as diamagnets, a strong increase in the 209Bi line intensities being observed in external magnetic fields. An approach based on registration of the quadrupole spin-echo envelopes enabled to reveal small (within an inhomogeneous line broadening) splittings in some other compounds of this type. The modeling of time dependence of the quadrupole spin echo amplitude indicated that modulations of the spin echo envelope in BaBiO2Cl and Bi3B5O12 resulted from weak (≤5 G) local magnetic fields. By using this approach, it was found that an increase in the 209Bi resonance intensity in external magnetic fields is related to an influence of the fields on the nuclear spin-spin relaxation rate for the appropriate compounds.

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References

  1. Kravchenko, E.A., Orlov, V.G.: Local magnetic fields in some bismuth compounds. A survey of experimental evidences. Z. Naturforshch.: Phys. Sci. 49A, 418–424 (1994)

    Google Scholar 

  2. Kravchenko, E.A., Orlov, V.G., Fam S.H., Kargin, Yu.F.: 209Bi NQR and magnetic properties of bismuth oxide-based compounds. Z. Naturforshch.: Phys. Sci. 53A, 504–513 (1998)

    Google Scholar 

  3. Kravchenko, E.A., Kargin, Yu.F., Orlov, V.G., Okuda, T., Yamada, K.: Local magnetic fields in Bi4Ge3O12. 209Bi NQR in weak magnetic fields. J. Magn. Magn. Mater. 224(3), 249–259 (2001)

    Article  ADS  Google Scholar 

  4. Kravchenko, E.A., Orlov, V.G., Shlykov, M.P.: Magnetic properties of bismuth(III) oxy compounds. Russ. Chem. Rev. 75(1), 77–94 (2006)

    Article  Google Scholar 

  5. Kravchenko, E.A., Morgunov, V.G., Kargin, Yu.F., Egorysheva, A.V., Orlov, V.G., Shlykov, M.P.: NQR indications of unconventional magnetism in some bismuth-based diamagnets. Appl. Magn. Reson 27(1–2), 65–75 (2004)

    Article  Google Scholar 

  6. Bloom, M., Hahn, E.L., Herzog, R.: Free magnetic induction in nuclear quadrupole resonance. Phys. Rev. 97(6), 1699–1709 (1955)

    Article  ADS  Google Scholar 

  7. Kennard, M.A., Darriet, J., Grannec, J., Tressand, A.J.: Cation ordering in the sillén X1-type oxychloride, BaBiO2Cl. Solid State Chem. 117, 201–205 (1995)

    Article  ADS  Google Scholar 

  8. Kravchenko, E.A., Morgunov, V.G., Orlov, V.G., Kargin, Yu.F.: Quadrupole spin-echo envelopes for Bi4Ge3O12 single crystals doped with atoms of transition and rare earth elements. JETP Lett. 86(5), 337–339 (2007)

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    E. A. Kravchenko & V. G. Morgunov

  2. Russian Research Center “Kurchatov Institute”, Moscow, 123181, Russia

    V. G. Orlov & M. P. Shlykov

Authors
  1. E. A. Kravchenko
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  2. V. G. Orlov
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  3. V. G. Morgunov
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  4. M. P. Shlykov
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Correspondence to E. A. Kravchenko.

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Kravchenko, E.A., Orlov, V.G., Morgunov, V.G. et al. Zero-field splittings of NQR spectra for bismuth(III) oxy compounds revealed by quadrupole spin echo envelopes. Hyperfine Interact 180, 7–10 (2007). https://doi.org/10.1007/s10751-008-9623-y

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  • DOI: https://doi.org/10.1007/s10751-008-9623-y

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