Abstract
Iron impurities on interstitial (Fei) and substitutional sites (FeS) in SiC have been detected by 57Fe emission Mössbauer spectroscopy following implantation of radioactive 57Mn+ parent ions. At temperatures <900 K two Fei species are found, assigned to quasi-tetrahedral interstitial sites surrounded by, respectively, four C (Fei,C) or Si atoms (Fei,Si). Above 900 K, the Fei,Si site is proposed to “transform” into the Fei,C site by a single Fei jump during the lifetime of the Mössbauer state (T 1/2 = 100 ns). Fei,C and substitutional FeS sites are stable up to >1,070 K.
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Gunnlaugsson, H.P., Bharuth-Ram, K., Dietrich, M. et al. Identification of substitutional and interstitial Fe in 6H-SiC. Hyperfine Interact 169, 1319–1323 (2006). https://doi.org/10.1007/s10751-006-9445-8
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DOI: https://doi.org/10.1007/s10751-006-9445-8