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The BM5Se9 phases: Mössbauer studies of the superconductors and the ferromagnets

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Abstract

Syntheses performed in the A3B/MSe2 (A = Sb, Ga, Sn) (B = Nb, V, Ta) (M = V, Nb, Ta) systems lead to the formation of B(M/A)5Se9 phases which could be ferromagnets or superconductors. It has been shown that the presence of V modifies the superconducting exchanges and allows ferromagnetic couplings. Mössbauer spectroscopy of both 121Sb and 119Sn gives local electronic structure of the SbNb5Se9 superconductor and the Sn0.94Ga0.06V0.30Nb4.70Se9 ferromagnet. For the latter compound, a complete study as a function of temperature is carried out showing that the Sn environment is not modified when the ferromagnetic transition occurs. The Debye temperature is calculated and compared to those obtained for other selenide compounds.

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References

  1. Molinié, P., Leblanc, A., Faulques, E., Ouilli, Z., Jumas, J.C., Ayache, C.: Spectroscopy of superconducting materials. In: Faulques, E. (ed.) American Chemical Society, Symposium series no. 730. Oxford University Press, Oxford (1999)

    Google Scholar 

  2. Leblanc-Soreau, A., Molinié, P., Jumas, J.C.: Physica B 321, 138 (2002)

    Article  ADS  Google Scholar 

  3. Ruebenbauer, K., Birschall, T.: Hyperfine Interact. 7, 125 (1975)

    Article  Google Scholar 

  4. Leblanc-Soreau, A., Molinié, P., Jumas, J.C.: Phys. Status Solidi (C) 1(7), 1846 (2004) 3(9), 3081 (2006)

    Article  ADS  Google Scholar 

  5. Fano, V., Ortalli, I.: J. Chem. Phys. 61, 5017 (1974)

    Article  Google Scholar 

  6. Herber, R.H.: Phys. Rev. B 27, 4013 (1983)

    Article  ADS  Google Scholar 

  7. Bodénan, F., Cajipe, V.P., Danot, M., Ouvrard, G.: J. Solid State Chem. 137, 249 (1998)

    Article  Google Scholar 

  8. Taylor, R.D., Graig, P.P.: Phys. Rev. 17, 782 (1968)

    Article  ADS  Google Scholar 

  9. Lippens, P.E.: Solid State Commun. 113, 399 (2000)

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. I.M.J.R.-CNRS, 2, rue de la Houssinière, BP 32229, 44322, Nantes Cedex 3, France

    A. Leblanc-Soreau

  2. LAMMI-CNRS, Place E. Bataillon, 34095, Montpellier Cedex 5, France

    J. C. Jumas & L. Aldon

Authors
  1. A. Leblanc-Soreau
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  2. J. C. Jumas
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  3. L. Aldon
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Correspondence to A. Leblanc-Soreau.

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Leblanc-Soreau, A., Jumas, J.C. & Aldon, L. The BM5Se9 phases: Mössbauer studies of the superconductors and the ferromagnets. Hyperfine Interact 168, 1211–1215 (2006). https://doi.org/10.1007/s10751-006-9426-y

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  • DOI: https://doi.org/10.1007/s10751-006-9426-y

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