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Effect of FeCl3 and acetone on the structure of Na–montmorillonite studied by Mössbauer and XRD measurements

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Abstract

57Fe Mössbauer spectroscopy, X-ray diffraction, X-ray fluorescence spectroscopy and infrared spectroscopy were used to study the effect of FeCl3 and acetone on the structure of a Na–bentonite. XRD indicated the incorporation of Fe3+ ions into the interlayer space since the basal lattice spacing of montmorillonite increased to 1.6 from 1.24 nm after treatment with FeCl3 dissolved in acetone. Interlayer Na+ ions could be exchanged to Fe3+. Magnetically split Mössbauer subspectra with internal magnetic fields 41 and 46 T at 74 K, were associated with two main Fe3+ microenvironments within the interlayer regions. The resultant Fe–montmorillonite was successfully applied as a catalyst in the preparation of 1,1-diacetates from aromatic aldehydes and acetic acid anhydride.

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Authors and Affiliations

  1. Isotope Laboratory, Department of Colloid Chemistry, Debrecen University, Debrecen, Hungary

    Andrea Komlósi, Noémi M. Nagy & József Kónya

  2. Research Group for Nuclear Methods in Structural Chemistry, Hungarian Academy of Sciences, Pázmány P. s. 1/a, Budapest, 1117, Hungary

    Ernő Kuzmann & Zoltán Homonnay

  3. Department of Nuclear Chemistry, Eötvös Loránd University, Pázmány P. s. 1/a, Budapest, 1117, Hungary

    Zoltán Homonnay & Shiro Kubuki

Authors
  1. Andrea Komlósi
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  2. Ernő Kuzmann
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  3. Zoltán Homonnay
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  4. Noémi M. Nagy
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  5. Shiro Kubuki
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  6. József Kónya
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Corresponding author

Correspondence to Ernő Kuzmann.

Additional information

Shiro Kubuki is on leave from Ube National College of Technology, Japan.

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Komlósi, A., Kuzmann, E., Homonnay, Z. et al. Effect of FeCl3 and acetone on the structure of Na–montmorillonite studied by Mössbauer and XRD measurements. Hyperfine Interact 166, 643–649 (2005). https://doi.org/10.1007/s10751-006-9335-0

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  • DOI: https://doi.org/10.1007/s10751-006-9335-0

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