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X-ray and Mössbauer study of structural changes in K3Na(FeO4)2

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Abstract

Mixed potassium–sodium ferrate(VI), K3Na(FeO4)2, has been synthesized by precipitation from alkaline solution. At room temperature it decomposes spontaneously giving Fe(III) compounds and ferrate(VI) with a structure similar to that of K2FeO4, which is confirmed by X-ray diffraction and Mössbauer spectroscopy.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, Russia

    S. K. Dedushenko, M. G. Zhizhin & Yu. D. Perfiliev

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  1. S. K. Dedushenko
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  2. M. G. Zhizhin
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  3. Yu. D. Perfiliev
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Correspondence to S. K. Dedushenko.

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Dedushenko, S.K., Zhizhin, M.G. & Perfiliev, Y.D. X-ray and Mössbauer study of structural changes in K3Na(FeO4)2 . Hyperfine Interact 166, 367–371 (2005). https://doi.org/10.1007/s10751-006-9294-5

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  • DOI: https://doi.org/10.1007/s10751-006-9294-5

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