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Rotational dynamics in anisotropic confinement

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Abstract

Quasi-elastic nuclear resonant forward scattering experiments of the model glass former DBP:FC (Dibutylphthalate:Ferrocene) have been performed in anisotropic confinement, yielding complex spectra. A model for the rotational relaxation of Ferrocene based upon the Kubo–Anderson process is presented, which explains the observed spectra as superposition of three components: Static Ferrocene, anisotropic rotating Ferrocene and isotropic rotating Ferrocene.

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Authors and Affiliations

  1. Hamburger Synchrotronstrahlungslabor, EMBL Hamburg Outstation, Hamburg, Germany

    G. Wellenreuther & H. Franz

  2. Physik Department, Institut für Experimentalphysik E13, TU München, Germany

    U. v. Bürck

  3. Nuclear Resonance Group, ESRF, Grenoble, France

    I. Sergueev

Authors
  1. G. Wellenreuther
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  2. H. Franz
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  3. U. v. Bürck
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  4. I. Sergueev
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Correspondence to G. Wellenreuther.

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Wellenreuther, G., Franz, H., Bürck, U.v. et al. Rotational dynamics in anisotropic confinement. Hyperfine Interact 165, 141–146 (2005). https://doi.org/10.1007/s10751-006-9257-x

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  • DOI: https://doi.org/10.1007/s10751-006-9257-x

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