Abstract
The process of burning of sulphur rich coal from Jaipur mine in North-Eastern India was carried out at a temperature of (675 ± 5) °C for different time intervals. 57Fe Mössbauer spectroscopy was applied to study the reaction products of iron compounds in each step of thermal treatment. The transformation of Szomolnokite (FeSO4·H2O) and Pyrite (FeS2) in the as received coal sample finally transformed to γ-Fe2O3 and α-Fe2O3. Other clay minerals produce some low spin silicate ash. Fourier Transmission Infrared (FT-IR) spectroscopy gives the ratio of several structural parameters such as H ar/H al and H ar/C ar. DTA analysis of the coal sample gives the exothermic reaction at different temperatures. TGA and TG analysis of the coal sample in an inert atmosphere shows the weight loss of the coal sample in different temperature ranges.
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References
Tissot, B., Welte, D.H.: Petroleum Formation and Occurrence. Springer, Berlin Heidelberg New York (1981)
Valero, A., Cortés, C.: Prog. Energy Combust. Sci. 22, 189 (1997)
Bolat, E., Saglam, S., Piskin, S.: Fuel Process Technol. 57, 93 (1998)
Wan, J.g., Tomita, A.: Fuel 77, 1747 (1998)
Jacobs, I.S., Levinson, L.M., HartJr, H.R.: J. Appl. Phys. 49, 1775 (1978)
Li, W.: Fuel Sci. Technol. Int. 14, 651 (1996)
Huffman, G.P., Huggins, F.E.: Fuel 57, 592 (1978)
Taneja, S.P., Jones, C.H.W.: Fuel 63, 695 (1984)
Montano, P.A.: Application of Mössbauer spectroscopy to coal characterization and utilization. In: Stevens, J.G., Shenoy, G.K. (eds.) Mössbauer Spectroscopy and its Chemical Applications, p. 235. American Chemical Society, Washington, District of Columbia (1981)
Shyu, H.J., Vaishnava, P.P., Montano, P.A.: Fuel 60, 1022 (1981)
Ram, L.C., Tripathi, S.P.M., Mishra, S.P.: Fuel Process Technol. 42, 47 (1995)
Tripathi, R.P., Shrivastavas, K.L.: Fuel 69, 928 (1990)
Ahmed, A.M., Blesa, M.J., Juan, R., Vandenberghe, R.E.: Fuel 82, 1825 (2003)
Waanders, F.B., Vinken, E., Mans, A., Mulaba-Bafubiandi, A.F.: Hyp. Int. 148, 21 (2003)
Bandyopadhyay, D., Singru, R.M., Biswas, A.K.: Minerals Engineering, 13(8–9), 973 (2000)
Mørup, S., Franck, J., Wonterghem, J., van Roy-Poulsen, H., Larsen, L.: Fuel 64, 528 (1985)
Srinivasachar, S., Helble, J.J., Boni, A.A.: Progress in Energy and Combustion Science 16(4), 281 (1990)
Verma, H.C., Tripathi, R.P.: Fuel 79, 599 (2000)
Ibarra, J.V., Muñoz, E., Moliner, I., Rafael: Org. Geochem 24, 725 (1996)
Brown, J.K., Lander, W.R.: Fuel 39, 87 (1960)
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Bandyopadhyay, D. Study of Kinetics of Iron Minerals in Coal by 57Fe Mössbauer and FT-IR Spectroscopy During Natural Burning. Hyperfine Interact 163, 167–176 (2005). https://doi.org/10.1007/s10751-006-9227-3
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DOI: https://doi.org/10.1007/s10751-006-9227-3