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Laser Ionization and Penning Trap Mass Spectrometry – A Fruitful Combination for Isomer Separation and High-precision Mass Measurements

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Abstract

We have demonstrated for the first time that element-selective laser ionization in combination with ultra-high resolution mass spectrometry can be used to prepare isomerically pure ion ensembles. Together with βγ coincidence studies this method allowed a determination of the low-energy structure and the unambiguous identification of triple β-decaying isomerism in 70Cu. By selective resonant ionization and measurement of the masses of these three states using ISOLTRAP at ISOLDE/CERN with a relative uncertainty of δm/m ≈ 5 ⋅ 10−8 a clear state-to-mass assignment was possible which resolved the assignment puzzle in 70Cu.

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Blaum, K., Beck, D., Bollen, G. et al. Laser Ionization and Penning Trap Mass Spectrometry – A Fruitful Combination for Isomer Separation and High-precision Mass Measurements. Hyperfine Interact 162, 173–179 (2005). https://doi.org/10.1007/s10751-005-9223-z

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