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A computer study of the absorption of infrared radiation by systems of molecular clusters

  • Heat and Mass Transfer and Physical Gasdynamics
  • Published:
High Temperature Aims and scope

Abstract

The method of molecular dynamics is used to investigate the process of absorption of N2O and CH4 molecules by water clusters and to determine the frequency spectra of permittivity for systems consisting of clusters mixed in different ratios, namely, (H2O)n, (N2O)i(H2O)10, and (CH4)i(H2O)10. IR-radiation absorption spectra for these systems are calculated and analyzed; the radiation power scattered by these systems and the tangent of dielectric loss angle are determined. The inclusion of anharmonicity of phonon oscillation makes it possible to explain the origin of characteristic frequencies appearing in IR spectra of mixtures of cluster systems. The capture of molecules of greenhouse gases by an ultradisperse aqueous medium affects the ability of this medium to absorb terrestrial radiation, i.e., reduces the greenhouse effect.

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References

  1. Dang, L.X. and Chang, T.-M., J. Chem. Phys., 1997, vol. 106, no. 19, p. 8149.

    Article  ADS  Google Scholar 

  2. Sremaniak, L.S., Perera, L., and Berkowitz, M.L., J. Chem. Phys., 1996, vol. 105, no. 9, p. 3715.

    Article  ADS  Google Scholar 

  3. Xantheas, S., J. Chem. Phys., 1996, vol. 104, no. 21, p. 8821.

    Article  ADS  Google Scholar 

  4. Feller, D. and Dixon, D.A., J. Chem. Phys., 1996, vol. 100, no. 8, p. 2993.

    Article  Google Scholar 

  5. Spackman, M.A., J. Chem. Phys., 1986, vol. 85, no. 11, p. 6579.

    Article  ADS  Google Scholar 

  6. Spackman, M.A., J. Chem. Phys., 1986, vol. 85, no. 11, p. 6587.

    Article  ADS  Google Scholar 

  7. Haile, J.M., Molecular Dynamics Simulation. Elementary Methods, New York: Wiley, 1992.

    Google Scholar 

  8. Koshlyakov, V.N., Zadachi dinamiki tverdogo tela i prikladnoi teorii giroskopov (Problems in Dynamics of Solids and Applied Theory of Gyroscopes), Moscow: Nauka, 1985.

    Google Scholar 

  9. Sonnenschein, R., J. Comp. Phys., 1985, vol. 59, no. 2, p. 347.

    Article  Google Scholar 

  10. Galashev, A.E., Chukanov, V.N., and Rakhmanova, O.R., The Physical Properties of (H2O)n and CO2(H2O)n Clusters in Molecular-Dynamic Model, in Metastabilнnye sostoyaniya i fazovye perekhody (Metastable States and Phase Transitions), Dubrovina, E.N., Ed., Ekaterinburg: NISO, Ural. Div., Russian Acad. Sci., 2004, issue 7, p. 180.

    Google Scholar 

  11. Hermans, J., Pathiaseril, A., and Anderson, A., J. Am. Chem. Soc., 1988, vol. 110, no. 18, p. 5982.

    Article  Google Scholar 

  12. Anderson, J., Ullo, J.J., and Yip, S., J. Chem. Phys., 1987, vol. 87, no. 3, p. 1726.

    Article  ADS  Google Scholar 

  13. Bresme, F., J. Chem. Phys., 2001, vol. 115, no. 16, p. 7564.

    Article  ADS  Google Scholar 

  14. Bosma, W.B., Fried, L.E., and Mukamel, S., J. Chem. Phys., 1993, vol. 98, no. 6, p. 4413.

    Article  ADS  Google Scholar 

  15. Landau, L.D. and Lifshitz, E.M., Elektrodinamika sploshnykh sred (Electrodynamics of Continua), Moscow: Nauka, 1982, vol. 8.

    Google Scholar 

  16. Fizicheskaya entsiklopediya (Physical Encyclopedia), Prokhorov, A.M., Ed., Moscow: Sovetskaya Entsiklopediya, 1988, vol. 1, p. 702.

    Google Scholar 

  17. Galashev, A.E. and Chukanov, V.N., Kolloidn. Zh., 2004, vol. 66, no. 5, p. 588.

    Google Scholar 

  18. Neumann, M., J. Chem. Phys., 1985, vol. 82, no. 12, p. 5663.

    Article  ADS  Google Scholar 

  19. Neumann, M., J. Chem. Phys., 1986, vol. 85, no. 3, p. 1567.

    Article  ADS  Google Scholar 

  20. Angell, C.A. and Rodgers, V., J. Chem. Phys., 1984, vol. 80, no. 12, p. 6245.

    Article  ADS  Google Scholar 

  21. Goggin, P.L. and Carr, C., Far Infrared Spectroscopy and Aqueous Solutions. Water and Aqueous Solutions, Bristol: Hilger, 1986, vol. 37, p. 149.

    Google Scholar 

  22. Kozintsev, V.I., Belov, M.L., Gorodnichev, V.A., and Fedotov, Yu.V., Lazernyi optiko-akusticheskii analiz mnogokomponentnykh gazovykh smesei (Laser Acousto-Optical Analysis of Multicomponent Gas Mixtures), Moscow: Izd. MGTU (Moscow State Technical Univ.) im. Baumana, 2003.

    Google Scholar 

  23. March, N. H. and Parrinello, M., Collective Effects in Solids and Liquids, Bristol: Hilger, 1982. Translated under the title Kollektivnye effekty v tverdykh telah i zhidkostyakh, Moscow: Mir, 1986.

    Google Scholar 

  24. Poulet, A. and Mathieu, J. P., Vibrational Spectra and Symmetry of Crystals, Paris: Gordon & Breach, 1970. Translated under the title Kolebatelнnye spektry i simmetriya kristallov, Moscow: Mir, 1973.

    Google Scholar 

  25. Galashev, A.E., Rakhmanova, O.R., and Chukanov, V.N., Kolloidn. Zh., 2005, vol. 67, no. 3, p. 322.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Industrial Ecology, Ural Division, Russian Academy of Sciences, Ekaterinburg, Russia

    A. N. Novruzov, V. N. Chukanov, O. R. Rakhmanova & A. E. Galashev

Authors
  1. A. N. Novruzov
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  2. V. N. Chukanov
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  3. O. R. Rakhmanova
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  4. A. E. Galashev
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__________

Translated from Teplofizika Vysokikh Temperatur, Vol. 44, No. 6, 2006, pp. 935–942.

Original Russian Text Copyright © 2006 by A. N. Novruzov, V. N. Chukanov, O. R. Rakhmanova, and A. E. Galashev.

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Novruzov, A.N., Chukanov, V.N., Rakhmanova, O.R. et al. A computer study of the absorption of infrared radiation by systems of molecular clusters. High Temp 44, 932–940 (2006). https://doi.org/10.1007/s10740-006-0112-1

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  • DOI: https://doi.org/10.1007/s10740-006-0112-1

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