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Interaction of Thiacarbocyanine Polymethine Dyes with the Surface of Silver Bromide Sols

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Abstract

A number of thiacarbocyanine polymethine dyes before and after adsorption on the surface of AgBr grains was studied by the method of X-ray photoelectron spectroscopy. The mechanism of adsorption of thiacarbocyanine dyes was found to consist in the formation of bonds between sulfur atoms of heterocyclic rings of the dyes and atoms of the substrate. Adsorption of spectral sensitizers was shown to change the electronic state of dye molecules and the composition of the AgBr surface.

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Translated from Khimiya Vysokikh Energii, Vol. 39, No. 5, 2005, pp. 367–372.

Original Russian Text Copyright © 2005 by Guzenko, Yudin, Yatsyna, Kolesnikov.

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Guzenko, A.F., Yudin, A.L., Yatsyna, N.A. et al. Interaction of Thiacarbocyanine Polymethine Dyes with the Surface of Silver Bromide Sols. High Energy Chem 39, 318–323 (2005). https://doi.org/10.1007/s10733-005-0063-9

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  • DOI: https://doi.org/10.1007/s10733-005-0063-9

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