Abstract
Non-steady-state kinetic measurements on the radiation-initiated polymerization of diethylene glycol bis(methacryloyloxyethyl carbonate) (OKM-2) were made over a wide range of conversions at various reaction temperatures. The polymer-chain propagation and termination rate constants were determined and compared with those for other monomers and oligomers.
Similar content being viewed by others
REFERENCES
Berlin, A.A., Kefeli, T.Ya., and Korolev, G.V., Poliefirakrilaty (Polyether Acrylates), Moscow: Nauka, 1967.
Berlin, A.A., Korolev, G.V., Kefeli, T.Ya., and Sivergin, Yu.M., Akrilovye oligomery i materialy na ikh osnove (Acrylic Oligomers and Related Materials), Moscow: Khimiya, 1983.
Mezhikovskii, S.M., Fizikokhimiya reaktsionnosposobnykh oligomerov. Termodinamika, kinetika, struktura (Physical Chemistry of Reactive Oligomers: Thermodynamics, Kinetics, Structure), Moscow: Nauka, 1998.
Korolev, G.V., Usp. Khim., 2003, vol. 72, no.3, p. 222.
Roshchupkin, V.P. and Kurmaz, S.V., Usp. Khim., 2004, vol. 73, no.3, p. 247.
Barkalov, I.M. and Kiryukhin, D.P., J. Polym. Sci., 1983, vol. 21, no.6, p. 1401.
Barkalov, I.M. and Kiryukhin, D.P., Int. Rev. Phys. Chem., 1994, vol. 13, no.2, p. 337.
Munikhes, V.M., Kuzina, S.I., Kiryukhin, D.P., Mikhailov, A.I., and Barkalov, I.M., Vysokomol. Soedin., Ser. A, 1978, vol. 20, no.4, p. 810.
Palma, G., Busulini, L., and Lora, S., Eur. Polym. J., 1970, vol. 6, no.4, p. 453.
Berlin, A.A., Vysokomol. Soedin., Ser. A, 1970, vol. 12, no.12, p. 2313.
Munikhes, V.M., Berezin, M.P., Kiryukhin, D.P., Barkalov, I.M., and Korolev, G.V., Vysokomol. Soedin., Ser. A, 1986, vol. 28, no.2, p. 358.
Busulini, L., Lora, S., Palma, G., and Lunardon, G., Eur. Polym. J., 1972, vol. 8, no.4, p. 465.
Lora, S., Palma, G., Busulini, L., and Castilleti, B., Eur. Polym. J., 1974, vol. 10, no.12, p. 1223.
Busulini, L., Lora, S., and Bordin, P., Eur. Polym. J., 1976, vol. 12, no.5, p. 521.
Author information
Authors and Affiliations
Additional information
__________
Translated from Khimiya Vysokikh Energii, Vol. 39, No. 5, 2005, pp. 339–342.
Original Russian Text Copyright © 2005 by Kiryukhin.
Rights and permissions
About this article
Cite this article
Kiryukhin, D.P. Kinetics of Radiation-Initiated Network Polymerization of Diethylene Glycol Bis(methacryloyloxyethyl carbonate) (OKM-2). High Energy Chem 39, 291–294 (2005). https://doi.org/10.1007/s10733-005-0057-7
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10733-005-0057-7