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A Study on the Photochemical Transformations of p- and m-Nitrosonitrobenzenes

  • Photochemistry
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Abstract

Photochemical oxidation of p- and m-nitrosonitrobenzenes to corresponding dinitrobenzenes was studied. The reaction was described by a scheme involving two successive steps, with the rates of photochemical decomposition of isomeric nitrosonitrobenzenes being much higher than those of dinitrobenzenes. Oligomeric azo and azoxy compounds and the products of hydroxylation of the reaction medium were found as final products of the reaction upon long-term irradiation with UV light.

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  1. Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 603950, Russia

    S. V. Zelentsov & A. A. Logunov

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  1. S. V. Zelentsov
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  2. A. A. Logunov
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__________

Translated from Khimiya Vysokikh Energii, Vol. 39, No. 4, 2005, pp. 287–292.

Original Russian Text Copyright © 2005 by Zelentsov, Logunov.

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Zelentsov, S.V., Logunov, A.A. A Study on the Photochemical Transformations of p- and m-Nitrosonitrobenzenes. High Energy Chem 39, 244–249 (2005). https://doi.org/10.1007/s10733-005-0049-7

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  • DOI: https://doi.org/10.1007/s10733-005-0049-7

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