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Photoinduced Chemiluminescence in 9-Anthrone Solution

  • Photochemistry
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Abstract

Interaction of a photoirradiated anthrone solution in dioxane with an aqueous base solution (0.1 mol l−1 NaHCO3) was accompanied by chemiluminescence. The product possessing chemiluminescent activity was accumulated in the solution within three hours of continuous UV irradiation (λmax ∼ 365 nm). It was retained in the solution within several days after irradiation. This product was supposed to be dianthrol. The maximum of the chemiluminescence spectrum is at 540–555 nm, which shows that the chemiluminescence emitter is the anthrol anion.

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Authors and Affiliations

  1. Emanuel’ Institute of Biochemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia

    Yu. B. Tsaplev & R. F. Vasil’ev

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  1. Yu. B. Tsaplev
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  2. R. F. Vasil’ev
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Translated from Khimiya Vysokikh Energii, Vol. 39, No. 4, 2005, pp. 255–258.

Original Russian Text Copyright © 2005 by Tsaplev, Vasil’ev.

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Tsaplev, Y.B., Vasil’ev, R.F. Photoinduced Chemiluminescence in 9-Anthrone Solution. High Energy Chem 39, 212–215 (2005). https://doi.org/10.1007/s10733-005-0044-z

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  • DOI: https://doi.org/10.1007/s10733-005-0044-z

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