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Dielectric Properties and Phase Transition in the PbSe + PbSeO3 Composite Material

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Abstract

Electrochemical cells in the form of pressed pellets and polycrystalline films prepared from the PbSe + PbSeO3 two-phase composite are investigated by impedance spectroscopy. The dispersion analysis of the frequencies of the real and imaginary parts of the complex impedance made it possible to reveal a unified equivalent electric circuit for these cells and to calculate its parameters. The optical (εhf) and static (εlf) permittivities of the PbSe and PbSeO3 phases are determined. The permittivities εhf = 20–45 and εlf = 200–280 obtained for the PbSe phase are in reasonable agreement with the data available in the literature. The temperature dependences of the ac and dc resistances indicate that the PbSe + PbSeO3 composite undergoes a phase transition at a temperature T c ≅ 363 K.

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Authors and Affiliations

  1. St. Petersburg State University of Electrical Engineering, ul. Professora Popova 5, St. Petersburg, 197376, Russia

    V. V. Tomaev, V. P. Miroshkin & L. N. Gar'kin

  2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, St. Petersburg, 199155, Russia

    P. A. Tikhonov

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  1. V. V. Tomaev
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  2. V. P. Miroshkin
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  3. L. N. Gar'kin
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  4. P. A. Tikhonov
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Original Russian Text Copyright © 2005 by Fizika i Khimiya Stekla, Tomaev, Miroshkin, Gar'kin, Tikhonov.

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Tomaev, V.V., Miroshkin, V.P., Gar'kin, L.N. et al. Dielectric Properties and Phase Transition in the PbSe + PbSeO3 Composite Material. Glass Phys Chem 31, 812–819 (2005). https://doi.org/10.1007/s10720-005-0130-9

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  • DOI: https://doi.org/10.1007/s10720-005-0130-9

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