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Mass Spectrometric Study of the Thermodynamic Properties of Melts in the Cs2O-B2O3 System

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Abstract

The vapor composition, activities of the components, and Gibbs energies of melts in the Cs2O-B2O3 system at a temperature of 1020 K are determined by the Knudsen effusion mass spectrometric method. The activities of the components and the Gibbs energies of melts in the Cs2O-B2O3 system at a temperature of 1020 are calculated in the framework of the approach based on the generalized lattice theory of associated solutions with the use of the melt model including vacancies. It is demonstrated that the calculated and experimental thermodynamic properties are in reasonable agreement.

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Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, St. Petersburg, 199155, Russia

    V. L. Stolyarova, S. I. Lopatin, G. A. Sycheva & E. N. Plotnikov

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  1. V. L. Stolyarova
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  2. S. I. Lopatin
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  3. G. A. Sycheva
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  4. E. N. Plotnikov
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Original Russian Text Copyright © 2005 by Fizika i Khimiya Stekla, Stolyarova, Lopatin, Sycheva, Plotnikov.

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Stolyarova, V.L., Lopatin, S.I., Sycheva, G.A. et al. Mass Spectrometric Study of the Thermodynamic Properties of Melts in the Cs2O-B2O3 System. Glass Phys Chem 31, 789–796 (2005). https://doi.org/10.1007/s10720-005-0126-5

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  • DOI: https://doi.org/10.1007/s10720-005-0126-5

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