Abstract
Alkali gallosilicate glasses containing 1–8 mol % CeO2 after ion-exchange treatment in a NaNO3 melt at different temperatures are studied. The refractive index distributions in glasses with different cerium oxide contents are obtained, and the profiles of the Na2O concentration distribution in the samples containing 2 mol % CeO2 after ion-exchange treatment at temperatures T = 500–550°C are determined. It is revealed that, as the cerium oxide content increases, the interdiffusion coefficient decreases, whereas the refractive index increment increases. The results obtained are analyzed within the framework of the model of dopant segregation, according to which cerium undergoes selective incorporation and concentration displacement into polar microregions of the glass.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Il'in, V.G., Karapetyan, G.O., Remizov, N.V., Petrovskii, G.T., and Polyanskii, M.N., Optics of Grins (A Review), Usp. Nauch. Fotogr., 1985, vol. 23, pp. 106–121.
Glebov, L.B., Il'in, V.G., and Moiseev, V.V., Physicochemical Principles of the Ion-Exchange Synthesis of Gradient-Index Optic Elements, in Stekloobraznoe sostoyanie (The Vitreous State), Leningrad: Nauka, 1988, pp. 125–131.
Karapetyan, G.O., Arkhipova, L.N., and Tagantsev, D.K., Problems of Gradient-Index Optics, Priborostroenie, 1996, vol. 39, nos.5–6, pp. 31–62.
Bogomolova, L.D., Fedorov, A.C., Kubrunskaya, M.E., and Serpov, P.V., The Effect of Na-K Ion Exchange on Copper States in Sodium Silicate Glasses Containing CuO, J. Non-Cryst. Solids, 1985, vol. 69, nos.2–3, pp. 387–392.
Grunin, V.S., Moiseev, V.V., Permyakova, T.V., and Sokolova, E.A., Electron Paramagnetic Resonance Investigation of the Ion-Exchange Process in Glasses, in Tezisy dokladov VIII Vsesoyuznogo soveshchaniya po stekloobraznomu sostoyaniyu (Abstracts of Papers of the VIII All-Union Conference on the Vitreous State), Leningrad: Nauka, 1986, pp. 155–156.
Zhatkin, Yu.A. and Remizov, N.V., Spectroscopic Investigation of Doped Ion-Exchanged Glasses, Fiz. Khim. Stekla, 1990, vol. 7, no.2, pp. 213–218.
Bocharova, T.V., Il'in, V.G., and Karapetyan, G.O., New Potentialities of Using the Diffusion Change in the Molar Volume in Optics, Tezisy dokladov VII Vsesoyuznogo simpoziuma po opticheskim i spektral'nym svoistvam stekol (Abstracts of Papers of the VII All-Union Symposium on Optical and Spectral Properties of Glasses), Leningrad: Vavilov State Optical Institute, 1989, pp. 201–202.
Bocharova, T.V., Il'in, V.D., and Karapetyan, G.O., A Method for Fabricating Glass Microlens Arrays, USSR Inventor's Certificate no. 1446579, Byull. Izobret., 1988, no. 47, p. 17.
Remizov, N.V., Development of the Physical Principles Underlying the Design of Vitreous Insulators, Extended Abstract of Candidate's Dissertation in Mathematical Physics, Leningrad: Leningrad Polytechnical Institute, 1984.
Ershova, T.T., Zykova, T.A., Moiseev, V.V., and Permyakova, T.V., Ion-Exchange Interaction of Lithium Silicate Glasses (Containing Sesquioxides) with Sodium and Silver Nitrate Melts, Fiz. Khim. Stekla, 1980, vol. 6, no.4, pp. 428–434.
Alaev, V.Ya., Zhatkin, Yu.A., Karapetyan, G.O., Moiseev, V.V., and Remizov, N.V., Cation Interdiffusion and Change in the Refractive Index of Gallium Silicate and Gallium Germanate Glasses, Fiz. Khim. Stekla, 1989, vol. 15, no.2, pp. 239–244.
Dubrovo, S.K. and Tsekhomskaya, T.S., Vitreous Lithium Gallium Silicates, Zh. Prikl. Khim. (St. Petersburg), 1963, vol. 37, no.6, pp. 1222–1227.
Murthy, M.K. and Emery, K., Properties and Structure of Glasses in the System M 2O-Ga2O3-GeO3 (M = Li, Na, K), Phys. Chem. Glasses, 1967, vol. 8, no.1, pp. 26–29.
Berezhnoi, A.I., Sitally i fotositally (Glass Ceramics and Photosensitive Glass Ceramics), Moscow: Mashinostroenie, 1981.
Il'in, V.G., Karapetyan, G.O., Karov, D.D., and Remizov, N.V., On the Determination of the Initial Refractive-Index Gradient upon Ion Exchange between Glass and Molten Salt, Fiz. Khim. Stekla, 1986, vol. 12, no.3, pp. 333–337.
Karapetyan, G.O., Luminescence of Cerium-Containing Glasses, Izv. Akad. Nauk SSSR, Ser. Fiz., 1959, vol. 23, no.11, pp. 1382–1386.
Wargin, W.W. and Karapetjan, G.O., Absorptionsspektren und Luminescenz Cer-haltiger Glasser, Glastech. Ber., 1959, vol. 32, no.11, pp. 443–450.
Galant, E.I. and Karapetyan, G.O., Structure of Doped Glasses, in Trudy V Vsesoyuznogo soveshchaniya po stekloobraznomu sostoyaniyu (Proceedings of the V All-Union Conference on the Vitreous State), Leningrad: Nauka, 1971, pp. 60–62.
Dmitryuk, A.V., Karapetyan, G.O., and Maksimov, L.V., Phenomenon of the Dopant Segregation and Its Spectroscopic Consequences, Zh. Prikl. Spektrosk., 1975, vol. 22, no.1, pp. 153–182.
Karapetyan, G.O., Color Centers and Luminescence in Glasses, in Tezisy dokladov XV Vsesoyuznogo soveshchaniya po lyuminestsentsii (Abstracts of Papers of the XV All-Union Conference on Luminescence), Tbilisi, 1966, pp. 19–20.
Author information
Authors and Affiliations
Additional information
Original Russian Text Copyright © 2005 by Fizika i Khimiya Stekla, Bocharova, Zhatkin, Karapetyan.
Rights and permissions
About this article
Cite this article
Bocharova, T.V., Zhatkin, Y.A. & Karapetyan, G.O. Effect of Cerium on the Ion-Exchange Parameters in Alkali Silicate Glasses. Glass Phys Chem 31, 602–605 (2005). https://doi.org/10.1007/s10720-005-0103-z
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10720-005-0103-z