Skip to main content
Log in

Effects of Binary Oxide Coated MWCNTs Toward Tailoring the Mechanical, Thermo-Mechanical, and Microstructural Properties of Pressureless Sintered MgAl2O4 Spinel Ceramic Composite

  • Published:
Glass and Ceramics Aims and scope Submit manuscript

This study presents a performance evaluation of MgAl-binary oxide-coated multi-walled carbon nanotubes (MWCNTs) as a reinforcement phase in a magnesium aluminate spinel (MgAl2O4) ceramic composite system fabricated using a pressureless sintering technique. The physical properties, including porosity, bulk density, and flexural strength of spinel composites were evaluated in the temperature range of 1500 – 1600°C. The results reveal the coated MWCNTs architecture’s promising influence on the composite system’s property enhancement. The developed thin-film coating on the MWCNTs favors enhanced dispersibility with better matrix-reinforcement interfacial connectivity, thereby improving the mechanical and thermo-mechanical performance of the composites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

References

  1. O. Vasylkiv, Y. Sakka, and V. V. Skorokhod, “Hardness and fracture toughness of alumina-doped tetragonal zirconia with different yttria contents,” Mater. Trans., 44(10), 2235 – 2238 (2003).

    Article  CAS  Google Scholar 

  2. R. S. Ruoff and D. C. Lorents, “Mechanical and thermal properties of carbon nanotubes,” Carbon, 33(7), 925 – 930 (1995).

    Article  CAS  Google Scholar 

  3. S. S. Samal and S. Bal, “Carbon nanotube reinforced ceramic matrix composites – a review,” J. Minerals Mater. Charact. Eng., 07(04), 355 – 370 (2008).

    Google Scholar 

  4. I. Ahmad, B. Yazdani, and Y. Zhu, “Recent advances on carbon nanotubes and graphene reinforced ceramics nanocomposites,” Nanomaterials, 5(1), 90 – 114 (2015).

    Article  Google Scholar 

  5. C. Nie, H. Wang, and J. He, “Evaluation of the effect of adding carbon nanotubes on the effective mechanical properties of ceramic particulate aluminum matrix composites,” Mech. Mater., 142, 103276 (2020).

    Article  Google Scholar 

  6. A. Gomathi, S. R. C. Vivekchand, A. Govindaraj, and C. N. R. Rao, “Chemically bonded ceramic oxide coatings on carbon nanotubes and inorganic nanowires,” Adv. Mater., 17(22), 2757 – 2761 (2005).

    Article  CAS  Google Scholar 

  7. S. Mukhopadhyay, S. A. Ansar, D. Paul, G. Bhowmick, and S. Sengupta, “Characteristics of refractory castables containing mullite and spinel coated graphites,” Mater. Manuf. Process., 27(2), 177 – 184 (2012).

    Article  CAS  Google Scholar 

  8. P. Das, S. Dutta, N. Das, and S. Mukhopadhyay, “Extended studies on surface-treated graphite vis-à-vis its application in high alumina refractory castable,” Int. J. Appl. Ceram. Tec., 15(3), 668 – 677 (2018).

    Article  CAS  Google Scholar 

  9. S. Mukhopadhyay, C. Mondal, A. Chakraborty, D. Mali, and S. Ghosh, “In-depth studies on cementitious nanocoatings on graphite for its contribution in corrosion resistance of alumina based refractory composite,” Ceram. Int., 41(9, Part B), 11,999 – 12,010 (2015).

  10. A. A. Leonov, A. O. Khasanov, V. A. Danchenko, and O. L. Khasanov, IOP Conf. Ser.: Mater. Sci. Eng., Int. Conf. Modern Tech. Mater. New Gen., Tomsk, Russia (2017).

  11. P. Das, S. K. Sharma, and B. K. Sanfui, “Engineering of the structural and morphological characteristics of MWCNTs employing a nano-dimensional binary oxide coating with enhanced thermal oxidation resistance properties for the tailoring of their reinforcement potential,” New J. Chem., 46(13), 5975 – 5995 (2022).

    Article  CAS  Google Scholar 

  12. P. Das, S. K. Sharma, and B. K. Sanfui, Enhancement of Thermal Oxidation Resistance Properties of MWCNTs by MgAl-Binary Oxide Coating and Its Preparation Thereof, Indian Patent (Filed), Application No: 202131045889 (2021).

  13. P. Das, S. K. Sharma, and B. K. Sanfui, An Energy Efficient Process for the Production of Magnesium Aluminate Spinel Ceramic, Indian Patent (Filed), Application no: 202131017942 (2021).

  14. I. Ahmad, M. Unwin, H. Cao, H. Chen, H. Zhao, A. Kennedy, and Y. Q. Zhu, “Multi-walled carbon nanotubes reinforced Al2O3 nanocomposites: Mechanical properties and interfacial investigations,” Compos. Sci. Technol., 70(8), 1199 – 1206 (2010).

    Article  CAS  Google Scholar 

  15. O. Hanzel, J. Sedlacek, and P. Sajgalik, “New approach for distribution of carbon nanotubes in alumina matrix,” J. Eur. Ceram. Soc., 34(7), 1845 – 1851 (2014).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Paromita Das.

Additional information

Translated from Steklo i Keramika, No. 10, pp. 61 – 63, October, 2023.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Das, P., Sharma, S.K., Mukhopadhyay, S. et al. Effects of Binary Oxide Coated MWCNTs Toward Tailoring the Mechanical, Thermo-Mechanical, and Microstructural Properties of Pressureless Sintered MgAl2O4 Spinel Ceramic Composite. Glass Ceram 80, 445–450 (2024). https://doi.org/10.1007/s10717-023-00630-5

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10717-023-00630-5

Keywords

Navigation