Skip to main content

Advertisement

Log in

On the Use of Cobalt-Containing Metalurgical Waste to Obtain Colored Glass and Glass Enamel

  • Published:
Glass and Ceramics Aims and scope Submit manuscript

The results of an investigation of the basic indicators of cobalt-containing metallurgical wastes for use as a substitute for scarce expensive cobalt oxide in the production of colored sectional glass and ground glass enamel are presented. The chemical, mineralogical, and granulometric compositions were established experimentally, and a processing technology with Co3O4 36.45 wt.% released in a concentrate was proposed. The addition of this oxide made it possible to obtain blue glass, which confirms the applicability of cobalt-containing waste as a replacement for pure cobalt oxide. Likewise, experiments were performed to assess the possibility of using these wastes in obtaining glass enamel and physicochemical methods were used to investigate the obtained samples and the optimal conditions for obtaining cobalt oxide and its obtained amount as a chromophore and adhesion activator in the glass-enamel–metal system were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

References

  1. Survey of the Cobalt Market in the World and the CIS: Infomain Report [in Russian], Moscow (2017).

  2. I. M. Petrov, “Non-ferrous metallurgy in Russia: summary of the 30th anniversary (1992 – 2021), main trends and prognoses,” Mineral. Resursy Rossii, Ekonom. Uprav., No. 3 – 4, 75 – 78 (2022).

  3. M. I. Hoamberdiev, Z. K. Babaev, F. A. Mingulova, and M. Y. Yunusov, “Properties and application potential of Uzbek quartz sands (Eigenschaften und einsatzmöglichkeiten der quarzsande Usbekistans),” Keramische Zeitschrift, this link is disabled, 58(1), 4 – 6 (2006).

  4. F. A. Mingulova, Z. K. Babaev, M. Yu. Yunusov, and K. T. Khakimov, “Khodzhikulskoe quartz sand as a new raw material,” Glass Ceram., 59(7 – 8), 283 – 284 (2002).

  5. T. I. Artamonova, Practical Training on Technology of Glass and Sitalls [in Russian], Vysshaya shkola, Moscow (1996).

  6. A. Petzol’d and G. Peschmann, Handbook of Enamel and Enameling [Russian translation], Metallurgiya, Moscow (1990).

  7. S. S. Bel’skii, “Processing of wolframite concentrate,” Vest. IrGTU, 22(1), 186 – 193 (2018).

  8. Ya. L. Giller, Tables of Interplanar Distance [in Russian], Nedra, Moscow (1966), Vol. 2.

  9. V. N. Mikheev, X-Ray Determinant of Minerals [in Russian], Gosgeoltekhizdat, Moscow (1957).

  10. Y. Li, J. Zhao, Y. Dan, et al., “Low temperature aqueous synthesis of highly dispersed Co3O4 nanocubes and their electrocatalytic activity studies,” Chem. Eng. J., 166, 428 – 434 (2011).

    Article  CAS  Google Scholar 

  11. U. L. Mostovaya, Synthesis and Basic Colloid-Chemical Properties of Sols of Oxygen-Containing Cobalt Compounds, Author’s Abstract of Candidate’s Thesis [in Russian], Moscow (2014).

  12. A. A. Nepomyashchev, E. A. Yatsenko, andn A. P. Zubekhin, “Adhesion mechanism of heat-resistant glass-enamel coating with copper,” Zh. Prikl. Khim., 73(3), 446 – 447 (2000).

  13. I. I. Radishevskaya, L. A. Egorova, A. M. Shulpekov, and V. I. Vereshchagin, “Pigments based on iron and cobalt molybdophosphates for low-melting enamels,” Glass Ceram., 60(1 – 2), 21 – 22 (2003).

  14. Z. K. Babaev, Aspects of the Use of Raw Materials of Inorganic Origin in the Aral Sea Region and the Technology of Obtaining Glass Products Based on Them, Author’s Abstract of Candidate’s Thesis [in Russian], IONKh, Akad. Nauk Resp. Uzbekistan, Tashkent (2021).

  15. D. K. Agisheva, S. A. Zotova, T. A. Matveeva, and V. B. Svetlichnaya, Mathematical Statistics, Textbook [in Russian], VPI (branch) VolgGTU, Volgograd (2010).

  16. J. Devore and N. Farnum, Applied Statistics for Engineers and Scientists, Thompson, Belmont (2005).

    Google Scholar 

  17. A. P. Zubehina and V. E. Gorbatenko, Methods and Means of Research and Control in Glass Enameling, Textbook [in Russian], NGTU, Novocherkassk (1995).

  18. Yu. D. Tretyakov, “Solid-phase reactions,” Soros. Obraz. Zh., No. 4. 35 – 39 (1999).

  19. Yu. A. Brusentsov and A. M. Minaev, Fundamentals of Physics and Technology of Oxide Semiconductors [in Russian], Izd. TGTU, Tambov (2002).

  20. Yu. A. Fedotova, V. G. Baev, A. I. Lesnikovich, et al., “Magnetic properties and local configurations of 57Fe atoms in CoFe2O4 powders and CoFe2O4/PVA nanocomposites,” Fiz. Tverd. Tela, 53(4), 647 – 653 (2011).

    Google Scholar 

  21. A. I. Vlasov, K. A. Elsukov, and I. A. Kosolapov, Electron Microscopy: Textbook [in Russian], Izd. MGTU im. N. É. Baumana, Moscow (2011).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Yu. Yunusov.

Additional information

Translated from Steklo i Keramika, No. 8, pp. 10 – 18, August, 2022.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yunusov, M.Y., Babaev, Z.K., Matchonov, S.K. et al. On the Use of Cobalt-Containing Metalurgical Waste to Obtain Colored Glass and Glass Enamel. Glass Ceram 79, 300–305 (2022). https://doi.org/10.1007/s10717-022-00504-2

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10717-022-00504-2

Keywords

Navigation