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Properties and Structure of Iron-Containing Magnetic Glasses Based on BaB2O4–BaSiO3 Eutectic

The magnetic and some physicochemical properties of glasses based on barium-borosilicate eutectic doped with iron and lithium oxides were studied. The magnetic permeability increases with increasing content of Fe2O3. The character of magnetic permeability remains unchanged when Fe2O3 and Li2O are introduced simultaneously. The formation of structural motifs of barium hexaferrite in glass is responsible for magnetic properties. According to EPR data, some iron ions are present in tetrahedral coordination, incorporating into the structural mesh of the glass, and the others in octahedral coordination, acting as a modifier.

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  1. A. Stratienko, “Modern magnetic materials and inductive components,” Komponenty Tekhnol., No. 9, 162 – 166 (2006).

  2. M. A. Pogosyan, “Investigation of glass formation and physicochemical properties of iron-containing borate systems for the development of glasses with ferromagnetic properties,” in: 3rd Annual Scientific Conference of the Russo-Armenian (Slavic) University [in Russian], Erevan (2008), pp. 213 – 219.

  3. M. A. Pogosyan, N. E. Kristosturyan, and A. A. Badalyan, Investigation of the magnetic properties of iron-barium and iron-manganese-borate glasses,” in: 2nd International Conference on Chemistry and Chemical Technology, Erevan, 13 – 17 September 2010 [in Russian], Erevan (2010), pp. 138 – 140.

  4. M. A. Pogosyan and A. A. Zanginyan, “Investigation of the magnetic moment and magnetization of iron-containing borate glasses,” Vest. NPUA Khim. Prirodookhr. Tekhnol., No. 2, 57 – 67 (2018).

  5. M. A. Pogosyan and A. G. Timiryazev, “Atomic-force microscopy: an effective method of studying oxide glasses with ferromagnetic properties,” in: 4th Int. Conf. on Chemistry and Chemical Technology, Erevan, 14 – 18 September 2015 [in Russian], Erevan (2015), pp. 106 – 109.

  6. Hsing-I Hsiang, Chi-Shiung Hs, Chun-Chi Huangc, and Shen-Li Fuc, “Sintering behavior and dielectric properties of BaTiO

  7. ceramics with glass addition for internal capacitor of LTCC,” J. Alloys Compounds, 459(1 – 2), 307 – 310 (2008).

  8. R. Kondratyuk, “LTCC — low temperature jointly fired ceramics,” Nanoindustriya: Nauch.-Tekhn Zh., No. 2, 26 – 30 (2011).

  9. W. Wong-Ng, R. S. Roth, T. A. Vanderah, and H. F. McMurdie, “Phase equilibria and crystallography of ceramic oxides,” J. Res. Natl. Inst. Stand. Technol., 106, 1097 – 1134 (2001).

    CAS  Article  Google Scholar 

  10. GOST 10134.1–2017. Glass and Glassware. Methods of Determining Chemical Stability [in Russian], Standartinform, Moscow (2018).

  11. V. Vercamer, G. Lelong, H. Hijiya, et al., Diluted Fe3+ in silicate glasses: structural effects of Fe-redox state and matrix composition. An optical absorption and x-band/q-band EPR study,” J. Non-Cryst. Solids, 428, 138 – 145 (2015).

    CAS  Article  Google Scholar 

  12. E. A. Petrakovskaya, V. F. Pavlov, O. A. Bayukov, et al., “Study of the structural features of glass-like and glass-crystalline materials based on brown coal ash,” Fiz. Khim. Stekla, 21(3), 299 – 304 (1995).

    Google Scholar 

  13. D. Griscom, “Electron spin resonance in glasses,” J. Non-Cryst. Solids, 40(1–3), 211 – 272 (1980).

    CAS  Article  Google Scholar 

  14. A. G. Belous, O. I. V’yunov, E. V. Pashkova, et al., “Mössbauer study and magnetic properties of m-type barium hexaferrite doped with Co + Ti and Bi + Ti ions,” J. Phys. Chem. B, 110, 26477 – 26481 (2006).

    CAS  Article  Google Scholar 

  15. Yu. S. Radchenko and A. Levitskii, “Synthesis of tinted glaze coatings based on metadiabase,” Glass Ceram., 57(11 – 12), 427 – 430 (2000) [Steklo Keram., No. 12, 20 – 23 (2000)].

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Correspondence to A. K. Kostanyan.

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Translated from Steklo i Keramika, No. 11, pp. 10 – 15, November, 2021.

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Pogosyan, M.A., Kostanyan, A.K. & Manukyan, A.S. Properties and Structure of Iron-Containing Magnetic Glasses Based on BaB2O4–BaSiO3 Eutectic. Glass Ceram 78, 431–435 (2022).

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Key words

  • borosilicate glass
  • eutectic
  • magnetic permeability
  • thermal expansion
  • rhenium
  • x-ray phase analysis
  • paramagnetic resonance