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Crystallization and Luminescence of Ni2+-Doped Gallium-Germanium Silicate Glasses with Partial Al2O3 Substitution of Ga2O3

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The effect of added Al2O3, introduced by the substitution method, on the crystallization and spectral-luminescent properties of gallium germanosilicate glasses with γ-Ga2O3:Ni2+ nanocrystals was investigated. It was found that the Ni2+-luminescence efficiency increased on account of both an increase in the degree of crystallinity of glass with Al2O3 and an increase in the strength of the crystal field around the Ni2+ ions on account of Al3+ incorporation into the structure of the precipitated nanocrystals.

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References

  1. S. Zhou, G. Feng, B. Wu, et al., “Intense infrared luminescence in transparent glass-ceramics containing γ-Ga2O3: Ni2+ nanocrystals,” J. Phys. Chem. C, 111, 7335 – 7338 (2007).

    Article  CAS  Google Scholar 

  2. B. N. Samson, L. R. Pinckney, J. Wang, et al. “Nickel-doped nanocrystalline glass-ceramic fiber,” Opt. Lett., 27, 1309 – 1311 (2002).

    Article  CAS  Google Scholar 

  3. L. R. Pinckney, B. N. Samson, G. H. Beall, et al., “Transparent gallate spinel glass-ceramics,” Ceram. Trans., 137, 265 – 275 (2003).

    CAS  Google Scholar 

  4. O. V. Mazurin, G. P. Roskova, V. I. Averyanov, and T. V. Antropova, Two-Phase Glass: Structure, Properties, Application [in Russian], Nauka, Leningrad (1991).

    Google Scholar 

  5. L. Lin, R. Miao,W. Xie, et al., “In situ and tunable structuring of semiconductor-in-glass transparent composite,” Science, 24(1), 101984 (2021).

  6. H. Shigemura, M. Shojiya, R. Kanno, et al., “Optical property and local environment of Ni2+ in fluoride glasses,” J. Phys. Chem. B, 102, 1920 – 1925 (1998).

    Article  CAS  Google Scholar 

  7. J. R. Lakowicz, Principles of Fluorescence Spectroscopy [in Russian], Springer, NY (2006).

    Book  Google Scholar 

  8. J. Piguet and J. Shelby, “Transformation-range behavior of Li2O–(Al, Ga)2O3–SiO2 glasses,” J. Am. Ceram. Soc., 68, 232 – 233 (1985).

    Article  Google Scholar 

  9. M. Saad and M. Poulain, “Glass forming ability criterion,” Mater. Sci. Forum, 19 – 20, 11 – 18 (1987).

  10. A. Paleari, V. N. Sigaev, N. V. Golubev, et al., “Crystallization of nanoheterogeneities in Ga-containing germanosilicate glass: Dielectric and refractive response changes,” Acta Mater., 70, 19 – 29 (2014).

    Article  CAS  Google Scholar 

  11. T. Oshima, Y. Kato, E. Magome, et al., “Characterization of pseudomorphic γ-Ga2O3 and γ-Al2O3 films on MgAl2O4 substrates and the band-alignment at the coherent γ-Ga2O3 /Al2O3 heterojunction interface,” Jpn. J. Appl. Phys., 58, 060910 – 5 (2019).

    Article  CAS  Google Scholar 

  12. J. A. Duffy, “Chemical bonding in the oxides of the elements: A new appraisal,” J. Solid State Chem., 62, No. 2, 145 – 157 (1986).

    Article  CAS  Google Scholar 

  13. N. V. Golubev, E. S. Ignat’eva, A. A. Maurus, et al., “Photoluminescence of gallate glass-ceramics: Al2O3 influence,” Glass Ceram., 77(11), 415 – 418 (2020) [Steklo Keram., No. 11, 12 – 15 (2020].

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Authors and Affiliations

  1. D. I. Mendeleev University of Chemical Technology of Russia, Moscow, Russia

    E. S. Ignat’eva, N. V. Golubev & V. N. Sigaev

  2. A. M. Prokhorov Institute of General Physics and Dianov Scientific Center for Fiber Optics Moscow, Moscow, Russia

    V. M. Mashinskii & A. K. Senatorov

  3. B. I. Stepanov Institute of Physics, National Academy of Sciences of Belarus, Minsk, Belarus

    N. V. Varapai

Authors
  1. E. S. Ignat’eva
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  2. N. V. Golubev
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  3. V. M. Mashinskii
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  4. A. K. Senatorov
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  5. N. V. Varapai
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  6. V. N. Sigaev
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Corresponding author

Correspondence to N. V. Golubev.

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Translated from Steklo i Keramika, No. 10, pp. 11 – 17, October, 2021.

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Ignat’eva, E.S., Golubev, N.V., Mashinskii, V.M. et al. Crystallization and Luminescence of Ni2+-Doped Gallium-Germanium Silicate Glasses with Partial Al2O3 Substitution of Ga2O3. Glass Ceram 78, 392–396 (2022). https://doi.org/10.1007/s10717-022-00418-z

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  • DOI: https://doi.org/10.1007/s10717-022-00418-z

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