The interaction of orthophosphoric acid with the bismuth borate glasses having the compositions (weight content, %) 70Bi2O3 - 30B2O3, 70Bi2O3 - 27B2O3 - 3MoO3, 70Bi2O3 - 26.94B2O3 - 3.06GeO2 and the bismuth glass 80Bi2O3 - 7SiO2 - 10GeO2 - 3MoO3 was investigated. The kinetics of this process is described and the activation energy is calculated. It is shown that at short interaction times the process is limited by the chemical reaction stage, but with increasing interaction time the stage of diffusion through the sediment layer assumes the main role in the heterogeneous interaction. The optimal choice of the parameters of the chemical treatment of glass was made: 15 min at 373.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Notes
Here and below the weight content, %.
References
Kh. D. Mokhammed, V. A. Kutvitskii, M. A. Gol’dshtrakh, et al., “Use of heterogeneous structures based on oxide compounds of bismuth as chemical sensors,” Mikrosistem. Tekh., No. 12, 6 - 9 (2001).
E. N. Kablov, F. N. Karachevtsev, V. L. Stolyarova, et al., “Thermodynamics and vaporization of ceramics based on the Y2O3-ZrO2 system studied by KEMS,” J. Alloys Compounds, 794, 606 - 614 (2019).
N. Ye. Shchegoleva, A. S. Chainikova, and L. A. Orlova, “Investigation of the sintering process in the production of glass ceramics based on strontium aluminosilicate glass by the method of semi-dry pressing,” Aviats. Mater. Tekhnol., No. 4, 55 - 62 (2018); DOI: 10.18577/2071-9140-2018-0-4-55-62.
B. Yu. Kuznetsov, O. Yu. Sorokin, M. L. Vaganova, and I. V. Osin, “Synthesis of model high-temperature ceramic matrices by spark plasma sintering and study of their properties for obtaining composite materials,” Aviats. Mater. Tekhnol., No. 4, 37 - 44 (2018); DOI: 10.18577/2071-9140-2018-0-4-37-44.
S. S. Solntsev, V. S. Denisova, A. B. Agarkov, and S. V. Gavrilov, “Effect of glass additives of the BaO-Al2O3-SiO2 system on the properties of reaction-cured coatings for the protection of nickel alloys,” Tr. VIAM: Elektronnyi nauchn-Tekhn. Zh., No. 1, Art. 11 (2018); URL: http://www. viam-works.ru (date of circulation June 21, 2021); DOI: 10.18577/2307-6046-2018-0-1-11-11.
E. N. Kablov, O. V. Startsev, I. M. Medvedev, and I. S. Shelemba, “Fiber-optic sensors for monitoring corrosion processes at the nodes of aviation technology (review),” Aviats. Mater. Tekhnol., No. 3, 26 - 32 (2017). DOI: 10.18577/2071-9140-2017-0-3-26-34.
E. N. Kablov, “Innovative work at FGUP VIAM on the strategic directions of development of materials and technologies for their processing for the period up to 2030,” Aviats. Mater. Tekhnol., No. 1, 3 - 33 (2015); DOI: 10.18577/2071-9140-2015-0-1-3-33.
Kh. D. Mokhammed, V. A. Kutvitskii, M. A. Gol’dshtrakh, et al., “Use of heterogeneous structures based on oxide compounds of bismuth as chemical sensors,” Mikrosistem. Tekh., No. 12, 6 - 9 (2001).
F. N. Karachevtsev, Synthesis of Multicomponent Glasses and Heterostructures Based on the Bi2O3-B2O3-MoO3 System and Their Use for Analytical Control, Author’s Abstract of Candidate’s Thesis [in Russian], Lomonosov Moscow State Academy of Fine Chemical Technology, Moscow (2008).
Y. B. Saddeek, A. M. Abousehly, and S. I. Hussien, “Synthesis and several features of the Na2O-B2O3-Bi2O-MoO3 glasses,” J. Phys. D: Appl., 40, 4674 - 4681 (2007).
M. Drache and P. Conflant, “The Bi2O3-Sm2O3 system: Phase diagram and electrical properties,” J. Mater. Chem., 4(1), 649 - 653 (1991).
B. Delmont, Kinetics of Heterogeneous Reactions [Russian translation], Mir, Moscow (1972).
P. Barre, Kinetics of Heterogeneous Processes [Russian translation], Mir, Moscow (1976).
V. V. Mitrofanov and V. A. Fogel, Chemistry and Physics of Semiconductors [in Russian], Sudostroenie, Leningrad (1965).
V. A. Kutvitskii, L. P. Maslov, O. Yu. Zhukova, et al., “Sensor for joint determination of water vapor and hydrogen sulfide and method of its production, Pat. 2418295 RF No. 2009145014/28,” Byull. Izobr. Polezn. Modeli, No. 13 (2011), declared 12.04.2009, publ. 10.05.2011.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Steklo i Keramika, No. 10, pp. 3 - 10, October, 2021.
Rights and permissions
About this article
Cite this article
Kutvitskii, V.A., Romanova, I.A., Ostanina, O.I. et al. Interaction Kinetics of Bismuth Borate Glasses and Orthophosphoric Acid. Glass Ceram 78, 385–391 (2022). https://doi.org/10.1007/s10717-022-00417-0
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10717-022-00417-0