Nanocrystalline LiZnMn-ferrite powders were synthesized by solution combustion at various glycine-nitrate ratios (G/N = 0.2, 0.4, ..., 1.4). Elemental analysis showed that the composition of the obtained samples corresponds to the ferrite-spinel Li0.45Zn0.05Mn0.06Fe2.43O4. Scanning electron microscopy showed that the compositions possess a porous microstructure and a developed surface; x-ray phase analysis attests that the synthesized LiZnMnFe-spinel is single-phase and possesses a high degree of crystallinity (to 99%). It was shown that the magnetic and dielectric characteristics of the obtained samples systematically change depending on the redox ratio of the reaction mixture and reach maximum values at stoichiometric value G/N = 0.4 – 0.6.
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References
M. Sugimoto, “The past, present, and future of ferrites,” J. Am. Ceram. Soc., 82(2), 269 – 280 (1999).
U. Ozgur, Y. Alivov, and H. Morkos, “Microwave ferrites. Part 2: Passive components and electrical tuning,” J. Mater. Sci.: Mater. Electron., 20, 911 – 952 (2009).
T. V. Trofimova, S. V. Saikova, M. V. Panteleeva, et al., “Anionexchange synthesis of copper ferrite powders,” Steklo Keram., No. 2, 38 – 44 (2018); T. V. Trofimova, S. V. Saikova, M. V. Panteleeva, et al., “Anion-exchange synthesis of copper ferrite powders,” Glass Ceram., 75(1 – 2), 74 – 79 (2018).
S. V. Dyachenko, M. A. Vaseshenkova, K. D. Martinson, et al., “Synthesis and properties of magnetic fluids based on magnetite particles,” Zh. Prikl. Khim., 89(5), 553 – 559 (2016).
A. O. Merkushkin and Zo E Mo, “UREE-ferrite based ceramic,” Steklo Keram., No. 10, 25 – 27 (2011); A. O. Merkushkin and Zo E Mo, “UREE-ferrite based ceramic,” Glass Ceram., 68(9 – 10), 337 – 339 (2011).
K. D. Martinson, I. S. Kondrashkova, and V. I. Popkov, “Obtaining EuFeO3 nanocrystals by glycine nitrate combustion,” J. Appl. Chem., 90(8), 88 – 93 (2017).
I. S. Kondrashkova, K. D. Martinson, N. V. Zakharova, and V. I. Popkov, “Features of formation and photocatalytic activity of HoFeO3 nanocrystals obtained by heat-treatment of the products of glycine-nitrate combustion,” Zh. Obshchei Khim., 88, No. 12, 1943 – 1950 (2018).
V. I. Popkov, V. P. Tolstoy, and V. G. Semenov, “Synthesis of phase-pure superparamagnetic nanoparticles of ZnFe2O4 via thermal decomposition of zinc-iron layered double hydroxy sulphate,” J. Alloys Compd., 813, 152179 (2020).
D. H. K. Reddy and Y.-S. Yun, “Spinel ferrite magnetic adsorbents: alternative future materials for water purification?” Coord. Chem. Rev., 315, 90 – 111 (2016).
K. D. Martinson, I. S. Kondrashkova, S. O. Omarov, et al., “Magnetically recoverable catalyst based on porous nanocrystalline HoFeO3 for the process of n-hexane conversion,” Adv. Powder Technol., No. 31, 402 – 408 (2020); URL: https://doi.org/10.1016/j.apt.2019.10.033.
K. D. Martinson, S. S. Kozyritskaya, I. B. Panteleev, and V. I. Popkov, “Low coercivity ceramics based on LiZnMn ferrite synthesized via glycine-nitrate combustion,” Nanosystems: Phys., Chem., Mathem., 10(3), 313 – 317 (2019).
P. Naderi, S. M. Masoudpanah, and S. Alamolhoda, “Magnetic properties of Li0.5Fe2.5O4 nanoparticles synthesized by solution combustion method,” Appl. Phys. A, 123, 702 (2017).
M. L. S. Teo, L. B. Kong, Z.W. Li, et al., “Development of magneto-dielectric materials based on Li-ferrite ceramics. I. Densification behavior and microstructure development,” J. Alloys Compd., 459, 557 – 566 (2008).
C. Liu, Z. Lan, X. Jiang, et al., “Effects of sintering temperature and Bi2O3 content on microstructure and magnetic properties of LiZn ferrites,” J. Magn. Magn. Mater., 320, 1335 – 1339 (2008).
R. Guo, Z. Yu, X. Jiang, et al., “Dispersion spectra of permeability and permittivity for LiZnMn ferrite doped with Bi2O3,” IEEE Trans. Magn., 49(7), 4295 – 4298 (2013).
K. D. Martinson, I. B. Panteleev, A. P. Shevchik, and V. I. Popkov, “Effect of the Red/Ox ratio on the structure and magnetic behavior of Li0.5Fe2.5O4 nanocrystals synthesized by solution combustion approach,” Lett. Mater., 9(4), 475 – 479 (2019).
A. T. Nguyen, T. D. Nguyen, V. O. Mittova, et al., “Phase composition and magnetic properties of Ni1–xCoxFe2O4 nanocrystals with spinel structure, synthesized by coprecipitation,” Nanosystems: Phys. Chem. Math., 8(3), 371 – 377 (2017).
M. Dasari, G. R. Gajula, D. H. Rao, et al., “Lithium ferrite: The study on magnetic behavior and complex permittivity characteristics,” Proc. Appl. Ceram., 11(1), 7 – 12 (2017).
K. D. Martinson, I. A. Cherepkova, I. B. Panteleev, and V. I. Popkov, “Single-step solution-combustion synthesis of magnetically soft NiFe2O4 nanopowders with controllable parameters,” Int. J. Self-Propag. High-Temp. Synth., 28(4), 266 – 270 (2019).
R. Guo, Z. Yu, Y. Yang, et al., “Effects of Bi2O3 on FMR and microwave dielectric properties of LiZnMn ferrite,” J. Alloys Compd., 589, 1 – 4 (2014).
M. N. Smirnov, M. A. Kop’eva, E. N. Beresnev, et al., “Synthesis of Mg(Fe0.8Ga0.2)2O4 by burning gel using glycine and starch,” Zh. Neorg. Khim., 63(10), 1239 – 1243 (2018).
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Translated from Steklo i Keramika, No. 6, pp. 16 – 23, June, 2020.
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Martinson, K.D., Ivanov, A.A., Panteleev, I.B. et al. Pre-Ceramic Nanostructured Liznmn-Ferrite Powders: Synthesis, Structure, and Electromagnetic Properties. Glass Ceram 77, 215–220 (2020). https://doi.org/10.1007/s10717-020-00274-9
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DOI: https://doi.org/10.1007/s10717-020-00274-9