The sol-gel process of obtaining magnesium-aluminate spinel fibers from a fiber-forming precursor based on aluminum and magnesium polycarboxylates was studied. It was shown that in principle discrete fibers of stoichiometric spinel can be obtained by means of aerodynamic spraying. The results of surface morphology, fine structure, and phase composition studies of the fibers are presented. It is shown that the obtained fibers have a uniform and polycrystalline structure with practically no nonfibrous inclusions in the fibrous mass. The phase composition corresponds to the stoichiometry of spinel.
Similar content being viewed by others
References
E. N. Kablov, “Aerospace materials science,” Vse Materialy. Entsiklopedicheskii Spravochnik, No. 3, 2 – 14 (2008).
E. N. Kablov, “Strategic directions of development of materialsand their processing technologies for the period up to 2030,” Aviatsionnye materialy i tekhnologii, No. S, 7 – 17 (2012).
N. M. Varrik, “Heat-resistant fibers and heat and sound insulating fireproof materials,” Tr. VIAM: Elektron. Nauch.-Tekhn. Zh., No. 6, Art. 07 (2015), URL: http:www.viam-works.ru (accessed: December 03, 2018), DOI: 10.185772307-60462014-0-6-7-7.
V. G. Babashov and N. M. Varrik, “High-temperature flexible fibrous heat-insulating material,” Tr. VIAM: Elektron. Nauch.-tekhn. Zh., No. 1, Art. 03 (2015); URL: http: www.viam-works.ru (accessed: December 03, 2018), DOI: 10.185772307-6046-2015-0-1-3-3.
Ceramics from Magnesium-Aluminate Spinel: Internet Resource; URL: https:markmet.ruogneupornie-materialykeramikaiz-alyumomagnezialnoi-shpineli (Access date: 11062018).
Abdul-Majeed Azard and Teng Wan Dung, “Spinel producedvia self-heat-sustained (SUS) technique,” Mater. Res. Bull., 36, 1417 – 1430 (2001).
Aysun Özkan, Zerrin Günkaya, Gülden Tok, et al., “Life CycleCost Analysis of Magnesia Spinel Bric Production,” Sustainability, 8(7), 662 (2016); URL: https:www.mdpi.com 2071-105087662 (access date: 03.12.20), DOI: https: doi.org10.3390su8070662.
J.-Guang Li, Takayasy Ikagami, Jong Heun Lee, et al., “Awet-chemical process yielding reactive magnesium aluminate spinel (MgAl2O4) powder,” Ceram. Int., 27, 481 – 489 (2001).
Z. Ding, M. Zhang, and J. Han, “Synthesis of magnesium aluminate powders utilizing the solubility relationships in the Mg – Al – oxalic acid-H2O system,” Bulgar. J. Phys., 30, 152 – 157 (2003).
Li-Zhai Peia, Wan-Yun Yinb, Ji-Fen Wanga, et al., “Low temperature synthesis of magnesium oxide and spinel powders by sol-gel process,” Mater. Res., 13(3), 339 – 343 (2010).
Zhang Chunye, Shen Xiangqian, Zhou Jianxin, and Shen Jiangying, “Preparation of spinel ferrite CoFe2O4 fibers by organic gel-thermal decomposition process,” Rare Metal Mater. Eng., 37, 180 – 184 (2008).
Yin Liu and Richard M. Laine, “Spinel fibers from carboxylateprecursor,” J. Europ. Ceram. Soc., 19, 1949 – 1959 (1999).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Steklo i Keramika, No. 8, pp. 28 – 33, August, 2019.
Rights and permissions
About this article
Cite this article
Balinova, Y.A., Lyulyukina, G.Y. & Kolyshev, S.G. Magnesium-Aluminate Spinel Fibers Obtained by the Sol-Gel Method. Glass Ceram 76, 302–306 (2019). https://doi.org/10.1007/s10717-019-00188-1
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10717-019-00188-1