Phase formation is studied in the system BaCO3 + TiO2 by means of solid-phase reactions and synthesis from melt obtained by the action of concentrated solar radiation of different intensities. It is shown that barium metatitanate BaTiO3 in the cubic system forms at intensities up to 100 W/cm2. As the radiation intensity increases, a tetragonal phase of barium titanate forms. The barium titanates obtained have high permittivity (3000 – 3200) and low dielectric losses.
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F. Negas, R. S. Roth, H. S. Parker, and D. J. Minor, “Subsolidus phase relations in the BaTiO3–TiO2 system,” J. Solid State Chem., 9(3), 297 – 307 (1974).
G. J. McCarthy, W. B. Whie, and R. Roy, “Phase equilibria in the 1375°C isotherm of the system Sr–Ti–O,” J. Am. Ceram. Soc., 52, 463 – 467 (1969).
T. Hoshina, H. Kakemoto, T. Tsurumi, and S. Wada, “Size end temperature induced phase transition behaviors of barium titanate nanoparticles,” J. Appl. Phys., 99, 054311 (2006).
S. Pathak and V. B. Shenoy, “Size dependence of thermal expansion of nanostructures,” Phys. Rev. B, 72, 113404 (2005).
M. S. Paizullakhanov, Sh. R. Nurmatov, and Zh. Z. Shermatov, “Barium and strontium titanates synthesized in a concentrated light field,” Steklo Keram., No. 9, 14 – 16 (2013); M. S. Paizullakhanov, Sh. R. Nurmatov, and Zh. Z. Shermatov, “Barium and strontium titanates synthesized in a concentrated light field,” Glass Ceram., 70(9 – 10), 324 – 326 (2013).
S. V. Khalameida, “Particularities of the synthesis of nano-disperse barium titanate and investigation of its properties,” Khim. Fiz. Tekh. Povekhnosti, 1(4), 441 – 449 (2010).
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Translated from Steklo i Keramika, No. 3, pp. 16 – 19, March, 2016.
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Atabaev, I.G., Faiziev, S.A. & Paizullakhanov, M.S. Structure Formation in the System TiO2–BaCO3 in Concentrated Solar Radiation. Glass Ceram 73, 88–90 (2016). https://doi.org/10.1007/s10717-016-9831-x
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DOI: https://doi.org/10.1007/s10717-016-9831-x