The methods for synthesis and properties of luminophores based on aluminum yttrium garnets activated by rare-earth elements for LED sources of light are reviewed. The composition dependences of the spectral characteristics of the luminophores are presented.
Similar content being viewed by others
References
A. A. Setlur, “Phosphors for LED-based solid-state lighting,” in: The Electrochemical Society Interface (2009), Winter, pp. 32 – 36.
M. Medraj, “High temperature neutron diffraction study of the Al2O3–Y2O3 system,” J. Euro. Ceram. Soc., No. 26, 3515 – 3524 (2006).
C. H. Lu, H. C. Hong, and R. Jaganathan, “Sol-gel synthesis and photoluminescent properties of cerium-ion doped yttrium aluminium garnet powders,” J. Mater. Chem., No. 12, 2525 – 2530 (2002).
Y. Zhou, J. Lin, M. Yu, et al., “Synthesis-dependent luminescence properties of Y3Al5O12: Re3+ (Re = Ce, Sm, Tb) phosphors,” Mater. Lett., No. 56, 628 – 636 (2002).
S. K. Shi and J. Y. Wang, “Combustion synthesis of Eu3+ activated Y3Al5O12 phosphor nanoparticles,” J. Alloys Compounds, No. 327, 82 – 86 (2001).
L. Mancic, K. Marinkovic, B. A. Marinkovic, et al., “YAG : Ce3+ nanostructured particles obtained via spray pyrolysis of polymeric precursor solution,” J. Euro. Ceram. Soc., No. 30, 577 – 582 (2010).
H. Y. Yang, J. W. Chung, B. K. Moon, et al., “Enhancement of Photoluminescence in Y3Al5O12 :Eu3+ Ceramics by Li Doping,” J. Korean Phys. Soc., 52(1), 116 – 119 (2008).
Yu. D. Ivakin, M. N. Danchevskaya, P. A. Yanechko, and G. P. Murav’eva, “Kinetics and mechanism of low-temperature synthesis of yttrium-aluminum garnet,” Vestn. Moskovsk. Univ., Ser. 2, Khim., 41(2), 89 – 92 (2000).
Y. Pan, M. Wu, and Q. Su, “Comparative investigation on synthesis and photolumenescence of YAG:Ce phosphor,” Mater. Sci. Eng., No. 106, 251 – 256 (2004).
L. Chen, C. C. Lin, C. W. Yeh and R. S. Liu, “Light Converting Inorganic Phosphors for White Light-Emitting Diodes,” Materials, No. 3, 2172 – 2195 (2010).
A. Ellens and F. Zwaschka, Leuchtstoff für Lichtquellen und zugehörige Lichtquelle, International Patent Application No. EP1095998 A2 (2001).
H. Sun, X. Zhang, and Z. Bai, “Synthesis and characterization of nano-sized YAG : Ce, Sm spherical phosphors,” J. Rare Earths, 31(3), 231 – 234 (2013).
P. Wu and A. D. Pelton, “Coupled thermodynamic-phase diagram assessment of the rare earth oxide-aluminium oxide binary systems,” J. Alloys Compounds, 179(1 – 2), 259 – 287 (1992).
B. Cockayne, D. B. Gasson, D. Findlay, et al., “The growth and laser characteristics of yttrium-gadolinium-aluminium garnet single crystals,” J. Phys. Chem. Solids, 29(6), 905 – 910 (1968).
Y. D. Huh, Y. S. Cho, and Y. R. Do, “The optical properties of (Y1–x Gd x )3–z (Al1–y Ga y )5O12: Ce z phosphors for white LED,” Bull. Korean Chem. Soc., 23(10), 1435 (2002).
W. W. Holloway and M. Kestigian, “Optical properties of cerium- activated garnet crystals,” J. Opt. Soc. Am., 59(1), 60 – 63 (1969).
A. L. Allred, “Electronegativity values from thermochemical data,” J. Inorg. Nucl. Chem., 17(3 – 4), 215 – 221 (1961).
C. C. Chiang, M. S. Tsai, and M. H. Hon, “Preparation of cerium- activated GAG phosphor powders. Influence of Co-doping on crystallinity and luminescent properties,” J. Electrochem. Soc., 154(10), 326 – 329 (2007).
M. Nazarov, J. Sohn, and C. Yoon, “Cerium-europium double activated terbium aluminium garnet phosphor for LED application,” Samsung Electro-Mechanics Co, LTD (2006), pp. 365 – 372.
F. Kummer, F. Zwaschka, A. Ellens, et al., Luminous Substance for a Light Source and Light Source Associated Therewith, International Patent Application, No. US6669866 B1 (2003).
H. M. Lee, Y. S. Cheng, and C. Y. Huang, “The effect of MgO doping on the structure and photoluminescence of YAG : Tb phosphor,” J. Alloys Compounds, 479(1 – 2), 759 – 763 (2009).
G. N. Mel’nikov, S. P. Chernykh, and N. P. Soshchin, “Yellow- orange photoluminophore and light-emitting diode based on it, Patent No. 2010121214_05,” Byull. Izobr. Polezn. Modeli, No. 19, 2455335, 2 (2012).
Y. Liu, “Luminescence and energy transfer in Ca3Sc2Si3O12: Ce3+, Mn2+ white LED phosphors,” J. Luminescence, 133, 21 – 24 (2013).
X. J. Liu, H. L. Li, R. J. Xie, et al., “Spectroscopic properties of nano-sized cerium-doped lutetium aluminum garnet phosphors via sol-gel combustion process,” J. Luminescence, 124(1), 75 – 80 (2007).
A. Katelnikovas, “Synthesis and optical properties of yellow emitting garnet phosphors for pcLEDs,” J. Luminescence, 136, 17 – 25 (2013).
S. Ye, F. Xiao, Y. X. Pan, et al., “Phosphors in phosphorconverted white light-emitting diodes: Recent advances in materials, techniques and properties,” Mater. Sci. Eng. R: Reports, 71(1), 1 – 34.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Steklo i Keramika, No. 2, pp. 27 – 30, February, 2014.
Rights and permissions
About this article
Cite this article
Kim, V.K., Zakharov, A.I. & Chashchin, V.A. Luminophores Based on Aluminum Yttrium Garnet (Review). Glass Ceram 71, 64–67 (2014). https://doi.org/10.1007/s10717-014-9618-x
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10717-014-9618-x