Sheet glass from different manufacturers or the same manufacturer but produced in different periods differ by color hue and total light transmission, which depends not only on the total content of iron oxide in the raw material and glass but also on the displacement of the equilibrium Fe(II) ⇄ Fe(III). To ensure that the molten glass, technological process, and shaping are all of high quality the equilibrium state of different forms of iron must be stabilized. Concrete recommendations on stabilizing the equilibrium and monitoring the technological process are presented.
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References
GOST 25551–77. Ground Quartz Sand, Sandstone, Quartzite, and Vein Quartz for Glass Industry [in Russian], Gosstandart, Moscow (1977).
A. E. Tarasov, “New technologies: energy of glass,” Stroit. Mater., Oborud., Tekhnol. XXI Veka, No. 1, 37 – 38 (2010).
A. B. Atkarskaya and V. I. Kiyan, “Reasons for variation of the thermal conductivity of molten glass in an operating tank furnace,” Steklo Keram., No. 10, 8 – 10 (2001); A. B. Atkarskaya and V. I. Kiyan, “Reasons for variations in glass melt diathermancy in an operating tank furnace,” Glass Ceram., 58(9 – 10), 335 – 337 (2001).
A. P. Sivko, A. I. Kovalenko, L. P. Smirnova, et al., “Role of iron in making molten glass and mechanized molding of articles,” Steklo. Glass Russia, October, 16 – 18 (2007).
A. V. Atkarskaya and V. I. Kiyan, “Effect of the equilibrium of heterovalent forms of iron on the glassmaking temperature under commercial production conditions,” Steklo Keram., No. 6, 6 – 9 (2006); A. V. Atkarskaya and V. I. Kiyan, “The effect of equilibrium of heterovalent forms of iron on melting temperature and glass homogeneity in industrial production conditions,” Glass Ceram., 63(5 – 6), 179 – 183 (2006).
V. I. Kiyan, É. K. Polokhlivets, P. A. Krivoruchko, and A. B. Atkarskaya, “Redox potential of molten glass in a continuous technological cycle,” Steklo Keram., No. 11, 11 – 12 (1999); V. I. Kiyan, É. K. Polokhlivets, P. A. Krivoruchko, and A. B. Atkarskaya, “Redox potential of glass melt in a continuous technological process,” Glass Ceram., 56(11 – 12), 343 – 345 (1999).
I. I. Kitaigorodskii and S. I. Sil’vestrovich (eds.), Handbook of Glass Production [in Russian], Stroiizdat, Moscow (1963), Vol. 1.
N. I. Min’ko, “Effect of the redox potential of the mix on glass-making processes and glass properties,” in: 2nd Intern. Conf. Stekloprogress – XXI [in Russian], Saratov (2005), pp. 54 – 61.
N. I. Min’ko, “Effect of iron on the technology of and properties of glasses,” Steklo Mira,No. 2,2–3 (2006).
Yu. A. Guloyan, K. S. Katkova, T. I. Balandina, and A. G. Belyaeva, “Redox characteristics of mix and particulars of making container glass,” Steklo Keram., No. 11, 4 – 5 (1990); Yu. A. Guloyan, K. S. Katkova, T. I. Balandina, and A. G. Belyaeva, “Charge redox characteristics of container-glass melting,” Glass Ceram., 47(11), 415 – 418 (1990).
N. G. Lipin, L. A. Orlova, and N. A. Pankova, “Evaluation of the redox potentials of glass mixes,” Steklo Keram., No. 11 – 12, 12 – 13 (1993); N. G. Lipin, L. A. Orlova, and N. A. Pankova, “Estimation of the redox potentials of glass batches,” Glass Ceram., 50(11 – 12), 464 – 466 (1993).
N. F. Zhernovaya, N. I. Min’ko, V. I. Onishchuk, and L. I. Mel’nikova, “Effect of the redox potential of mix and cullet on the color of commercial glass compositions containing iron oxides,” Steklo Keram., No. 3, 11 – 13 (2000); N. F. Zhernovaya, N. I. Min’ko, V. I. Onishchuk, and L. I. Mel’nikova, “Effect of the redox potential of the glass batch and cullet on the tinting of industrially produced glass containing iron oxides,” Glass Ceram., 57(3 – 4), 84 – 86 (2000).
V. N. Vepreva, “Monitoring and stabilization of the redox potential of molten glass in the a vertical sheet-glass drawing system,” Steklo Keram., No. 7, 32 (1999); V. N. Vepreva, “Monitoring and stabilizing the glass melt redox potential in the vertical glass drawing system,” Glass Ceram., 56(11 – 12), 232 (1999).
N. A. Pankova, L. Ya. Levitin, I. V. Aleksandrova, and I. N. Gorina, “Methods for stabilizing the iron oxide content in glass,” Steklo Keram., No. 1, 4 – 5 (1980); N. A. Pankova, L. Ya. Levitin, I. V. Aleksandrova, and I. N. Gorina, “Methods of stabilizing the content of iron oxides in a glass composition,” Glass Ceram., 37(1),3–6 (1980).
N. I. Min’ko, S. N. Volkova, I. I. Miroshnichenko, et al., “Particulars of the structural state of iron in glass synthesized in an accelerated electron beam,” Fiz. Khim. Stekla, 16(6), 852 – 859 (1990).
N. D. Yatsenko, K. A. Verevkin, and A. P. Zubekhin, “Mössbauer spectroscopy study of the phase and crystal-chemical states of iron oxides in ceramic brick,” Steklo Keram., No. 6, 13 – 15 (2010); N. D. Yatsenko, K. A. Verevkin, and A. P. Zubekhin, “Mössbauer spectroscopy of phase and crystal-chemical states of iron oxides in ceramic brick,” Glass Ceram., 67(5– 6), 176 – 178 (2010).
V. I. Kiyan, Yu. I. Mashir, and A. B. Atkarskaya, “Change in the redox potential of molten glass with melting accelerator introduced into the batch,” Steklo Keram., No. 3, 5 – 7 (2000); V. I. Kiyan, Yu. I. Mashir, and A. B. Atkarskaya, “Change in the redox potential of a glass melt upon introducing a melting catalyst into the glass batch,” Glass Ceram., 57(3–4), 78–80 (2000).
“Monitoring the redox state in glass melt. Kuhnrecih-Meixner Company,” in: Reports at the 6th Inter. Conf. on Container and Art Glass XXI [in Russian], Gus’-Khrystal’nyi (2003), pp. 41 – 42.
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Translated from Steklo i Keramika, No. 3, pp. 18 – 21, March, 2011.
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Min’ko, N.I., Atkarskaya, A.B., Myagkaya, A.A. et al. Stabilizing the spectral properties and technologies of glass. Glass Ceram 68, 87 (2011). https://doi.org/10.1007/s10717-011-9328-6
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DOI: https://doi.org/10.1007/s10717-011-9328-6