IR spectroscopy and Raman scattering have been used to study the structure of multicomponent silicate glass with phosphorus oxide addition, simulating the commercial compositions of container glass and sheet float-glass. It is established that P2O5 addition gives a micro-nonuniform structure consisting of silicon oxide anionic groupings, with different degrees of connectedness, and orthophosphate groupings. Such nonuniformity promotes subsequent liquation and crystallization of multicomponent glasses containing phosphorus.
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Translated from Steklo i Keramika, No. 4, pp. 3–5, April, 2009.
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Mulevanov, S.V., Min’ko, N.I., Kemenov, S.A. et al. Vibrational spectroscopy investigation of the structure of multicomponent phosphorus-containing silicate glasses. Glass Ceram 66, 117–119 (2009). https://doi.org/10.1007/s10717-009-9137-3
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DOI: https://doi.org/10.1007/s10717-009-9137-3