Film Formation in Binary Sol-Gel Systems

Abstract

The film-forming capacity of binary systems containing Sb₂O₃, SnO₂, CeO₂, Y₂O₃, Nd₂O₃, Bi₂O₃, V₂O₅, ZnO, CuO, CdO, and Al₂O₃ are investigated. The best film-formers are Sb₂O₃ and SnO₂, whereas ZnO, CuO, CdO, and Al₂O₃ cannot produce films of optical quality. The rest of considered oxides do not impair the clarity of coatings when their molding content is 20 – 50%. A proportional dependence is established between the refractive index and the reflection coefficient of a film and the refractive indexes of oxides making parts of this film, as well as between the concentration of deposited FFS, the film-forming capacity of oxides, and the film thickness.